首页|MOF及其衍生催化剂电催化水分解的研究进展

MOF及其衍生催化剂电催化水分解的研究进展

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随着社会经济的快速发展,能源与环境问题越来越突出,解决问题的关键是寻找可持续的、可再生的绿色新能源.电催化水裂解技术在解决清洁能源短缺和环境污染等关键问题上具有突出的优势.金属有机骨架(metal-organic frameworks,MOFs)及其衍生物由于具有可定制的结构、超大的表面积和设计灵活性,被认为是电催化制氢的理想多孔材料.从电催化水裂解的反应原理、决定电催化活性的相关因素入手,总结并举例说明了近年来基于MOFs及其衍生物的水裂解电催化剂的研究进展.最后,强调了水裂解领域存在的许多挑战,并提出了基于MOFs和衍生物作为电催化剂用于水裂解制氢的展望.
Recent progress on electrocatalytic water splitting over metal-organic framework based-and derived-catalysts
Electrocatalytic water splitting exhibits outstanding advantages for solving the critical problems of clean energy shortage and environmental pollution.Electric driven water splitting is a promising strategy for producing clean and renewable hydrogen.Metal-organic frameworks(MOFs)and their derivatives are consid-ered as ideal porous materials for electrocatalytic H2 production,resulting from their tailorable structure,ultra-large surface area,and design flexibility.This review starts with the reaction principle of electrocatalytic water splitting,relevant factors that determine the electrocatalytic activity,and then summarizes and exemplifies the recent progress in the development of MOFs based-and derived-electrocatalysts for water splitting.Finally,we highlighted the many challenges exist in the water splitting field,and proposed some perspectives of MOFs based-and derived-electrocatalysts for H2 production from water splitting.

electrolysis of watermetal-organic frameworksderivativeselectrocatalysthydrogen evolution reac-tion

周雨蝶、裴刘军、靳凯丽、张馨儿、王际平

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上海工程技术大学纺织服装学院,上海 201620

上海纺织化学清洁生产工程技术中心,上海 201620

电解水 金属有机骨架 衍生物 电催化 析氢反应

国家自然科学基金项目安徽省重点研发项目海宁市科技计划工业、农业项目松江区科学技术攻关项目浙江省清洁染整技术研究重点实验室开放基金

220720892023t07020001202100323SJJBGS2QJRZ2301

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(8)