首页|冶炼烟气脱硝用碳基低温NH3-SCR催化剂研究进展

冶炼烟气脱硝用碳基低温NH3-SCR催化剂研究进展

扫码查看
目前在冶炼烟气治理脱硝中使用的NH3-SCR催化剂存在操作温度窗口窄、低温(120 ℃)下催化活性不高、易中毒等不足,限制了其广泛应用.因此,开发低温高效、抗中毒性能好、稳定性强的催化剂成为当前研究重点.碳基催化剂由于其来源广泛、吸附性能强、催化活性好等优点备受关注,在脱硝方面有广阔的前景.本文基于碳基低温NH3-SCR催化剂的最新研究进展,从碳基催化剂材料、添加活性组分、酸碱改性、抗SO2与H2O中毒与等方面介绍了影响催化剂脱硝活性的因素,分析了碳基催化剂的NH3-SCR脱硝反应机理,并提出利于研发低温NH3-SCR脱硝性能优异、抗中毒性能好的碳基催化剂的方向.
Research progress on carbon-based low-temperature NH3-SCR catalysts for smelting flue gas denitrification
At present,the NH3-SCR catalyst used in smelting flue gas treatment and denitrification has short-comings such as narrow operating temperature window,low catalytic activity at low temperature(120 ℃),and easy poisoning,which limits its wide application.Therefore,the development of catalysts with low temperature efficiency,good anti-toxicity performance and strong stability has become the focus of current research.Carbon-based catalysts have attracted much attention due to their wide range of sources,strong adsorption perform-ance,and good catalytic activity,and have broad prospects in denitrification.Based on the latest research pro-gress of carbon-based low-temperature NH3-SCR catalysts,the factors influencing the denitrification activity of catalysts were introduced from the aspects of carbon-based catalyst materials,addition of active components,acid or base modification,resistance to SO2 and H2O poisoning,and the NH3-SCR reaction mechanism of car-bon-based catalysts is analyzed,and the direction of carbon-based catalysts with excellent denitrification per-formance and anti-poisoning performance of low-temperature NH3-SCR is proposed.

denitrificationlow temperaturecarbon-basedsmelting flue gas

孟豪、折媛、苗红生、李纪萱、沈正华、邢相栋、张朝晖

展开 >

西安建筑科技大学冶金工程学院,西安 710055

西宁特殊钢股份有限公司,西宁 810000

脱硝 低温 碳基 冶炼烟气

陕西省科技厅重点研发计划项目榆林市科技局产学研合作项目陕西省创新能力支撑计划项目

2024GX-YBXM-4222023-CXY-1942023-CX-TD-53

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(8)