功能材料2024,Vol.55Issue(8) :8083-8089.DOI:10.3969/j.issn.1001-9731.2024.08.011

Co添加对FeSiBCuNb非晶纳米晶合金软磁性能的影响

Effect of Co element addition on soft magnetic properties of FeSiBCuNb amorphous nanocrystalline alloy

郭琦 李晓涵 王志成 金亚旭 张克维 胡季帆
功能材料2024,Vol.55Issue(8) :8083-8089.DOI:10.3969/j.issn.1001-9731.2024.08.011

Co添加对FeSiBCuNb非晶纳米晶合金软磁性能的影响

Effect of Co element addition on soft magnetic properties of FeSiBCuNb amorphous nanocrystalline alloy

郭琦 1李晓涵 1王志成 1金亚旭 1张克维 1胡季帆1
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作者信息

  • 1. 太原科技大学材料科学与工程学院,太原 030024
  • 折叠

摘要

通过单辊甩带法制备成分为Fe80.5-xCoxSi3.5B13.5Cu1Nb1.5(x=0,3,5,7,9)非晶合金带材,研究了 Co含量及退火温度对非晶纳米晶合金软磁性能与组织结构的影响.其中,退火温度为510 ℃,Co含量x=5时,Fe75.5Co5Si3.5B13.5Cu1Nb1.5非晶合金形成了由非晶基体和纳米晶粒组成的双相结构,晶粒尺寸D约为13.5 nm,具有低矫顽力Hc=2.5 A/m及高饱和磁感应强度Bs=1.59 T,获得了优异综合软磁性能.通过磁光克尔(magnet-ic-optical kerr,MOKE)显微镜观测合金表面磁畴结构,当退火温度为510 ℃,Co含量x=5时,内应力释放相对完全,纳米晶微观结构更加均匀,条状磁畴更清晰平直,磁畴的变化与Hc变化相对应.

Abstract

Amorphous alloy ribbons with nominal compositions of Fe80.5-xCoxSi3.5B13.5Cu1Nb1.5(x=0,3,5,7,9)were prepared by melt spinning technique,which is used to investigate the effects of Co content and annea-ling temperature on the soft magnetic properties and organization of amorphous nanocrystalline alloys.The Fe75.5Co5Si3.5B13.5Cu1Nb1.5 quenched amorphous alloy under annealing temperature of 510 ℃ form an amor-phous/nanocrystalline composite structure consisting of an amorphous matrix and nanograins and have excellent comprehensive soft magnetic properties,which contain the grain size D=13.5 nm,low coercivity Hc=2.5 A/m and high saturation magnetic induction intensity Bs=1.59 T.The magnetic domain structures on the surface of the ribbons at different annealing temperatures were observed by magnetic-optical kerr(MOKE)microscope.When the annealing temperature is 510 ℃ and the Co content x is 5,the internal stress release relative com-pletely,which leads to the uniform nanocrystalline microstructure and straight clearly striped domains,and the change of the magnetic domains corresponded to the change of Hc.

关键词

非晶纳米晶软磁合金/Co元素/矫顽力/磁畴/退火温度

Key words

amorphous nanocrystalline soft magnetic alloy/Co element/coercivity/magnetic domain/annealing temperature

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基金项目

国家自然科学基金项目(51901150)

山西省基础研究计划项目(20210302124535)

山西省基础研究计划项目(202103021223273)

天津市光电检测技术与系统重点实验室开放课题(2023LOTDS001)

天津市光电检测技术与系统重点实验室开放课题(2023LOTDS002)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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