首页|添加剂SiO2和CaCO3对M型锶铁氧体结构及磁性能的影响

添加剂SiO2和CaCO3对M型锶铁氧体结构及磁性能的影响

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采用固相法制备M型锶铁氧体,研究了球磨时间与添加剂含量对M型锶铁氧体微观形貌、晶体结构、磁性能的影响.实验结果显示,随着球磨时间的增加,样品的磁性能呈先增后减的趋势.在球磨时间为16h时,样品展现出最佳的磁性能,其Mr=66.35 A·m2/kg,Hc=140.9 KA/m,(BH)max=28.88 kJ/m3.此外,在添加剂含量上的研究同样发现,样品的磁性能呈现先增加后减小的趋势.具体而言,当添加剂为CaCO3时,最佳的添加量为1%(质量分数),此时(BH)max=29.36 kJ/m3,而当添加剂为SiO2时,最佳添加量为0.2%(质量分数),此时(BH)max=34.63 kJ/m3,Hc=337.0 KA/m,Mr=65.01 A·m2/kg.实验结果表明通过调节球磨时间和添加剂含量可以改善锶铁氧体的孔隙率,进而提高该材料的磁性能.
Effect of heat treatment of pastes on the structure and properties of M-type strontium ferrites
M-type strontium ferrite was prepared using the solid-phase method.The effects of ball milling time and additive content on the microscopic morphology,crystal structure,and magnetic properties of M-type strontium ferrite were investigated.The experimental results showed that the magnetic properties of the sam-ples increased and then decreased with the increase of ball milling time.After 16 hours of ball milling,the sam-ple demonstrates the most favourable magnetic properties,with Hc=140.9 kA/m,Mr=66.35 A·m2/kg,and(BH)max=28.88 kJ/m3.Furthermore,the study on the additive content shows that the magnetic properties of the sample tend to increase initially and then decrease.When using CaCO3 as the additive,the optimal addition amount is 1wt%,resulting in(BH)max=29.36 kJ/m3.On the other hand,when using SiO2 as the additive,the optimal addition amount is 0.2wt%,resulting in(BH)max=34.63 kJ/m3,Hc=337.0 kA/m,and Mr=65.01 A·m2/kg.The experimental results demonstrate that adjusting the ball milling time and additive content can en-hance the porosity of strontium ferrite,thereby improving its magnetic properties.

strontium ferriteball milling timeadditivesmicro-structuremagnetic properties

任相如、席永曈、罗琳、张云川、罗现福、钟光伟、马毅龙

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重庆科技大学化学化工学院,重庆 401331

重庆科技大学冶金与材料工程学院,重庆 401331

重庆凌达磁材科技有限公司,重庆 402560

锶铁氧体 球磨时间 添加剂 微观结构 磁性能

国家自然科学基金青年基金项目重庆市自然科学基金项目重庆科技大学研究生科技创新项目

52102089CSTB2023NSCQ-MSX0447YKJCX2320217

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(8)