功能材料2024,Vol.55Issue(8) :8214-8220.DOI:10.3969/j.issn.1001-9731.2024.08.029

Ce介电增强WO3在摩擦纳米发电机中的应用

Ce dielectric enhanced WO3 for application in triboelectric nanogenerator

任远航 谢远航 张雨涵 陈杰 万步勇 杨晓红
功能材料2024,Vol.55Issue(8) :8214-8220.DOI:10.3969/j.issn.1001-9731.2024.08.029

Ce介电增强WO3在摩擦纳米发电机中的应用

Ce dielectric enhanced WO3 for application in triboelectric nanogenerator

任远航 1谢远航 1张雨涵 1陈杰 1万步勇 1杨晓红1
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作者信息

  • 1. 重庆师范大学物理与电子工程学院,重庆 401331
  • 折叠

摘要

采用水热法制备 WO3和Ce掺杂的 WO3(Ce∶WO3)纳米颗粒,以Ce∶WO3填充聚二甲基硅氧烷(PDMS)制备复合膜,研究Ce掺杂对WO3颗粒及复合膜介电性能的影响,并以Ce∶WO3/PDMS复合膜作为摩擦纳米发电机(TENG)的摩擦层(Ce∶WO3/PDMS-TENG),研究Ce介电增强WO3对TENG输出性能的影响.结果表明Ce掺杂对WO3纳米颗粒的晶体结构和晶粒尺寸几乎没有影响,但能有效增强纳米WO3的介电性能,介电常数由9.99提升至20.83.体积比为8%、掺杂比1.5%Ce∶WO3/PDMS-TENG,相比纯PDMS-TENG输出性能有显著提升,开路电压由114 V提升至279 V、短路电流由1.38 μA提升至7.02 μA、转移电荷由35.7nC提升至 99.7nC.

Abstract

WO3 and Ce-doped WO3(Ce∶WO3)nanoparticles were prepared by a hydrothermal method,and the Ce∶WO3 filled polydimethylsiloxane(PDMS)composite membranes were prepared.The influence of Ce doping on the dielectric properties of WO3 particles and composite membranes were studied.And the Ce∶WO3/PDMS composite membranes was used as the friction layer of TENG(Ce∶WO3/PDMS-TENG)to study the effect of Ce dielectric enhancement of WO3 on the output performance of TENG.The results indicate that the Ce-doping has no effect on the crystal structure and grain size of WO3 nanoparticle,but the relative dielectric constant of WO3 can be effectively increased from 9.99 to 20.83.Compared with the pure PDMS-TENG,the output per-formance of 1.5 mol%Ce∶WO3/PDMS-TENG was significantly improved,with an increase in the open-circuit voltage from 114 V to 279 V,the short-circuit current from 1.38 μA to 7.02 μA,and the transferred charge from 35.7 nC to 99.7 nC.

关键词

WO3颗粒/Ce掺杂/介电常数/摩擦纳米发电机

Key words

WO3 particles/Ce doping/dielectric constant/triboelectric nanogenerator

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基金项目

国家自然科学基金(52302219)

重庆市教委重点科技项目(KJZD-K202200505)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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