首页|镁空气电池阳极用Mg-Sr合金的放电性能研究

镁空气电池阳极用Mg-Sr合金的放电性能研究

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采用电化学技术和镁空气电池放电测试系统地研究了 Mg-xSr(x=0.2%,0.5%,1%,2%和4%)(质量分数)5种合金作为镁空气电池阳极材料的耐蚀性及放电性能.结果表明,在镁合金中添加适量的Sr元素时,可以有效的增强合金的耐蚀性和电化学活性.在所研究的阳极里,Mg-2Sr阳极在所有电流密度下都具有最高且相对稳定的放电电压且表现出最好的放电性能,在40 mA/cm2下具有最高的阳极效率,为68%.随着Sr含量的进一步增加,过量的第二相加速了自腐蚀,合金的耐蚀性和放电性能下降.
Study on the discharge performance of Mg-Sr alloy for magnesium-air battery anode
In this study,the corrosion resistance and discharge properties of five alloys of Mg-xSr(x=0.2wt%,0.5wt%,1wt%,2wt%and4wt%)as anode materials for magnesium-air batteries were systematically studied by electrochemical techniques and magnesium-air battery discharge test.The results show that the corrosion re-sistance and electrochemical activity of the alloy can be effectively enhanced when an appropriate amount of Sr is added to the magnesium alloy.Among the anodes studied,the Mg-2Sr anode had the highest and relatively sta-ble discharge voltage and the best discharge performance at all current densities,and had the highest anode effi-ciency of 68%at 40 mA/cm.With the further increase of Sr content,the excess second phase accelerates self-corrosion,and the corrosion resistance and discharge performance of the alloy decrease.

magnesium alloyMg-air batteriesmicrostructureelectrochemical propertiesdischarge performance

原宇坤、栗东虎、侯利锋、杜华云、王骞、卫英慧

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太原理工大学材料科学与工程学院,太原 030024

山西省金属材料腐蚀与防护工程技术中心,太原 030024

镁合金 镁空气电池 微观组织 电化学性能 放电性能

国家自然科学基金项目吕梁市引进高层次科技人才重点研发项目

52071227Rc2020-109

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(9)
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