首页|硅藻土基自粘附超疏水防腐涂层的制备

硅藻土基自粘附超疏水防腐涂层的制备

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金属是工业和日常生活最常用的原材料之一,金属设备遍及生活的方方面面.但是随着使用时间的延长,这些设备将不可避免的发生锈蚀,严重降低设备性能、缩短服役寿命,甚至可能导致安全事故事故的发生,因此延缓金属的腐蚀至关重要.长久以来,涂覆有机涂层法是最便捷高效的防腐措施.超疏水涂层凭借独特的材料特性和巧妙的表面结构,不仅能够阻止腐蚀性介质的入侵,同时可以延缓污垢的附着.在这次研究中,以硅藻(DE)土为"桥梁",将具有Cl-固化效果的Ni-Co LDH和Fe3O4磁性纳米材料进行组装,并进行疏水改性,制备了磁性疏水Fe3O4/Ni-Co/DE磁性微胶囊填料,实现了硅藻微胶囊的Cl-固化和疏水的协同防腐.另外,将获得的磁性疏水填料与聚偏二氟乙烯(PVDF)混合,制备了具有钢铁自粘附特性的疏水防护涂层.测试结果表明自粘附涂层最大疏水角为151.52°,在模拟海水中浸泡20 d后最优异自粘附涂层的阻抗模值仍然高达1011 Ω·cm2,表现出优异的自清洁和防腐蚀性能.
Preparation of diatomite-based self-adhesive super-hydrophobic anti-corrosion coating
Industrial production and daily life are inseparable from steel tools and equipment,but with the exten-sion of the use of time,carbon steel equipment will inevitably occur corrosion,which will reduce the mechanical and physical properties of carbon steel,shorten the service life,waste economy at the same time may cause fire,explosion and other catastrophic accidents,so the corrosion of carbon steel is very important.So electrochemical method,organic coating method,corrosion inhibitor method and other common methods are designed to solve such problems.Among them,the organic coating method is the most convenient and the best effect,and among all kinds of coatings,the superhydrophobic coating has attracted the attention of researchers because of its u-nique surface structure and excellent anti-corrosion performance.However,the coating prepared by the existing method usually requires a large number of organic solvents,which is not only a complicated process,but also causes serious environmental pollution,and the later maintenance work is very complicated.Therefore,it is necessary to prepare a self-adhesive and self-cleaning coating which is not limited by time,space and thermal spraying equipment for the protection of carbon steel equipment.In this study,a preparation method was intro-duced.The anti-corrosion coating with self-adhesion,self-adsorption and long-term superhydrophobic properties was prepared by scraping coating through secondary hydrothermal method,and relevant tests were carried out on it.The results show that the modified composite coating has a maximum hydrophobic Angle of 151.52° and an impedance modulus of 1011 Ω·cm2,showing excellent self-cleaning and anti-corrosion properties.

superhydrophobic coatingdiatomitePVDFfunctional coatingself-adsorption

杨磊、陈世波、张彦弛、刘书佩、张欣芳、饶劲松

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烟台市招远市中广核新能源工程事业部,烟台 264000

潍坊东方钢管有限公司,潍坊市 261000

重庆大学材料科学与工程学院,重庆 400044

超疏水涂层 硅藻土 PVDF 功能涂层 自吸附

国家自然科学基金项目重庆市研究生科研创新项目重庆市重大主题专项

52072053CYS22005cstc2019jscxzdztzxX0047

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(9)
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