首页|紫外光照对氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料导热性能的影响

紫外光照对氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料导热性能的影响

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以PVB为基底,碳纳米管和氮化硼为填料,采用溶液共混法制备成复合材料,并针对波长范围、照射时长和辐照强度3种影响因素,开展了人工紫外照射实验,通过瞬态电热技术测量了不同波长、不同照射时长和不同辐照强度下复合材料的热扩散系数和导热系数.结果表明,氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料对波长为340 nm的光照射线更为敏感,且随着照射时间的增长或者辐照强度的增大,材料内部结构会发生断裂和降解,使得其热扩散系数呈不断下降的趋势.
Effect of ultraviolet illumination on the thermal conductivity of boron nitride/carbon nanotube/polyvinyl butyral composites
The composites were prepared by solution blending method using PVB as substrate and carbon nano-tubes and boron nitride as fillers.Artificial ultraviolet irradiation experiments were carried out based on three influencing factors:wavelength range,irradiation time and irradiation intensity.The thermal diffusivity of the composites at different wavelengths,irradiation times and irradiation intensities was measured by transient elec-trocalorimetric technique.The results show that the boron nitride/carbon nanotube/poly(vinyl butyral)com-posites are more sensitive to the light rays at a wavelength of 340 nm,and with the increase of irradiation time or intensity,the internal structure of the material will be fractured and degraded,resulting in a continuous de-crease in its thermal diffusivity.

composite materialsultraviolet radiationthermal conductivitytransient electrothermal technologypolyvinyl butyral

申福花、张媛娟、徐锦波、张立军、肖贵勇、林欢

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青岛理工大学环境与市政工程学院,山东青岛 266000

青岛理工大学工程质量检测鉴定中心有限公司,山东青岛 266033

复合材料 紫外辐射 导热性能 瞬态电热技术 聚乙烯醇缩丁醛

国家重点研发计划项目基金资助项目山东省自然科学基金资助项目

2019YFE0119900ZR2020ME183

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(10)