功能材料2024,Vol.55Issue(10) :10047-10052.DOI:10.3969/j.issn.1001-9731.2024.10.007

紫外光照对氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料导热性能的影响

Effect of ultraviolet illumination on the thermal conductivity of boron nitride/carbon nanotube/polyvinyl butyral composites

申福花 张媛娟 徐锦波 张立军 肖贵勇 林欢
功能材料2024,Vol.55Issue(10) :10047-10052.DOI:10.3969/j.issn.1001-9731.2024.10.007

紫外光照对氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料导热性能的影响

Effect of ultraviolet illumination on the thermal conductivity of boron nitride/carbon nanotube/polyvinyl butyral composites

申福花 1张媛娟 1徐锦波 1张立军 1肖贵勇 2林欢1
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作者信息

  • 1. 青岛理工大学环境与市政工程学院,山东青岛 266000
  • 2. 青岛理工大学工程质量检测鉴定中心有限公司,山东青岛 266033
  • 折叠

摘要

以PVB为基底,碳纳米管和氮化硼为填料,采用溶液共混法制备成复合材料,并针对波长范围、照射时长和辐照强度3种影响因素,开展了人工紫外照射实验,通过瞬态电热技术测量了不同波长、不同照射时长和不同辐照强度下复合材料的热扩散系数和导热系数.结果表明,氮化硼/碳纳米管/聚乙烯醇缩丁醛复合材料对波长为340 nm的光照射线更为敏感,且随着照射时间的增长或者辐照强度的增大,材料内部结构会发生断裂和降解,使得其热扩散系数呈不断下降的趋势.

Abstract

The composites were prepared by solution blending method using PVB as substrate and carbon nano-tubes and boron nitride as fillers.Artificial ultraviolet irradiation experiments were carried out based on three influencing factors:wavelength range,irradiation time and irradiation intensity.The thermal diffusivity of the composites at different wavelengths,irradiation times and irradiation intensities was measured by transient elec-trocalorimetric technique.The results show that the boron nitride/carbon nanotube/poly(vinyl butyral)com-posites are more sensitive to the light rays at a wavelength of 340 nm,and with the increase of irradiation time or intensity,the internal structure of the material will be fractured and degraded,resulting in a continuous de-crease in its thermal diffusivity.

关键词

复合材料/紫外辐射/导热性能/瞬态电热技术/聚乙烯醇缩丁醛

Key words

composite materials/ultraviolet radiation/thermal conductivity/transient electrothermal technology/polyvinyl butyral

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基金项目

国家重点研发计划项目基金资助项目(2019YFE0119900)

山东省自然科学基金资助项目(ZR2020ME183)

出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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