首页|TiO2-SiO2复合材料的制备及其光催化性能研究

TiO2-SiO2复合材料的制备及其光催化性能研究

扫码查看
采用溶胶凝胶法制备了一种新型的TiO2-SiO2复合材料,并考察了其光催化降解染料废水中罗丹明B(RhB)的效率.通过X射线衍射(XRD),透射电子显微镜(TEM),扫描电子显微镜(SEM),X射线光电子能谱(XPS),光致发光光谱(PL)等仪器对制备的样品进行表征.结果表明,TiO2与SiO2的结合抑制了锐钛矿向金红石的转变,从而减小了电子-空穴的复合几率.研究发现,当SiO2含量为40%,煅烧温度为800 ℃时,TiO2-SiO2复合材料具有最高的光催化活性.此外,复合材料具有良好的催化稳定性,在光催化降解RhB过程中·O2-是主要的活性物种.
Preparation and photocatalytic performance of TiO2-SiO2 composites
In this paper,a new TiO2-SiO2 composite was prepared by sol-gel and the efficiency of rhodamine B(RhB)in photocatalytic dye wastewater was investigated.The samples were characterized by X-ray diffraction(XRD),transmission electron microscope(TEM),scanning electron microscope(SEM),X-ray photoelectron spectroscopy(XPS),photoluminescence spectroscopy(PL)and other instruments.The results show that the binding of TiO2 to SiO2 inhibits the anatase to rutile transition,thus reducing the chance of an electron-hole re-combination.We found that the TiO2-SiO2 composites had the highest photocatalytic activity when the SiO2 content was 40%and the calcination temperature was 800 ℃.Moreover,the composites have good catalytic sta-bility,and·O2-is the main active species during the photocatalytic degradation of RhB.

titanium dioxidesilicarhodamine Bdegradation

李康宁、丁庆伟、秦荔妍、李凯、马骏

展开 >

太原科技大学环境与资源学院,太原 030024

二氧化钛 二氧化硅 罗丹明B 降解

山西省回国留学人员科研项目山西省回国留学人员科研项目山西省自然科学基金太原科技大学博士科研启动基金国家级大学生创新创业训练计划项目

2021-011HGKY2019082201901D11124920192012202210109014

2024

功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
年,卷(期):2024.55(10)