功能材料2024,Vol.55Issue(12) :12016-12020.DOI:10.3969/j.issn.1001-9731.2024.12.003

纳米晶NiTiV记忆合金的超弹性研究

Study on superelasticity of nanocrystalline NiTiV memory alloys

李诗翰 李秋真 郭精远 郝世杰 崔立山
功能材料2024,Vol.55Issue(12) :12016-12020.DOI:10.3969/j.issn.1001-9731.2024.12.003

纳米晶NiTiV记忆合金的超弹性研究

Study on superelasticity of nanocrystalline NiTiV memory alloys

李诗翰 1李秋真 1郭精远 1郝世杰 1崔立山1
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作者信息

  • 1. 中国石油大学(北京)新能源与材料学院,北京 102249
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摘要

NiTi基记忆合金的超弹温域较窄(<100℃),限制了其应用范围.通过Ni、V元素共掺杂NiTi,采用真空感应熔炼、锻造、大变形拔丝及低温退火制备出纳米晶(NC)Ni51Ti49V1(%原子分数)合金丝材,利用透射电镜(TEM)表征样品的微观组织,万能拉伸试验机表征样品的超弹性.结果表明,NC Ni51Ti49V1合金为等轴纳米晶,平均晶粒尺寸为13 nm;在不同温度下进行拉伸测试,合金在-40~+100 ℃的宽温域内表现出优异超弹性,超弹温域宽于NC NiTi合金(25~100 ℃);另外Ni5iTi49V1合金B2→B19'相变的临界应力温度依赖性(dσ/dT)随温度的降低而降低,从5.6 MPa/℃非线性降低至1.8 MPa/℃.

Abstract

NiTi based memory alloys have a narrow super-elastic temperature range(<100 ℃),which limits their application range.In this paper,nanocrystalline(NC)Ni51Ti49V1(at.%)alloy wire was prepared by Ni-V co-doped NiTi through vacuum induction melting,forging,large deformation wire drawing and low tempera-ture annealing.The microstructure of the sample was characterized by transmission electron microscopy(TEM),and the superelasticity of the sample was characterized by universal tensile testing machine.The re-sults showed that Ni51Ti49V1 alloy consists of nanocrystalline with an average grain size of 13 nm.Tensile tests at different temperatures showed that the alloy exhibited excellent superelasticity in a wide temperature range from-40 ℃ to 100 ℃,and the superelastic temperature range was wider than that of NC NiTi alloy(25-100 ℃).In addition,the temperature dependence of the critical stress of the B2→B19'transformation(dσ/dT)de-creased from 5.6 MPa/℃ to 1.8 MPa/℃ with decreasing temperature.

关键词

NiTiV记忆合金/纳米晶/超弹性/温度依赖性

Key words

NiTiV memory alloy/nanocrystalline/superelasticity/temperature dependence

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出版年

2024
功能材料
重庆材料研究院 中国仪器仪表学会仪表材料学会

功能材料

CSTPCD北大核心
影响因子:0.918
ISSN:1001-9731
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