首页|新疆哈密恐龙骨骼化石风化原因分析

新疆哈密恐龙骨骼化石风化原因分析

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新疆早白垩世哈密翼龙动物群中恐龙化石的发现,增加了动物群的多样性,也为恐龙的系统演化提供了新的信息,具有重要的科学意义.然而,哈密恐龙化石在脱离原始埋藏环境在异地保存时,由于保存环境的改变,化石出现严重的风化现象.为了使哈密恐龙化石能够得到更好的保存、研究和展陈,采用多种分析技术方法,对产生明显风化现象的哈密恐龙骨骼化石进行检测,分析导致化石风化破碎的原因.X射线衍射(XRD)结果显示,哈密恐龙骨骼化石风化严重区域是骨松质部分,其主要矿物成分为石英和方解石,含有较少磷灰石、长石和黏土矿物等.其中石英和长石是充填骨松质孔隙中的外来碎屑颗粒,方解石是后期成岩或化石风化过程中形成的胶结物,而少量的磷灰石则主要来自骨骼.离子色谱(IC)、傅里叶变换红外光谱(FTIR)、拉曼光谱(Raman)以及扫描电子显微镜能谱仪(SEM-EDS)的结果表明,哈密恐龙骨骼化石风化区域的可溶盐以NaCl、CaCl2和Ca(NO3)2·4H2O为主,以及少量CaSO4,可溶盐含量高达2.63%,初步判断高可溶盐含量是造成化石出现严重风化现象的主要原因.压汞(MIP)测试结果表明,哈密恐龙骨骼化石风化区域的孔隙率为21.272 2%,与未风化区域16.420 6%的孔隙率相比显著增大.另外,恐龙骨骼化石风化区域存在两种孔径分布的孔隙,尺寸分别为0.005~0.04和17.3~283.2μm,相较于未风化区域,风化区域产生较多微裂隙,大孔径孔隙数量急剧增多.结论认为化石中含有大量以CaCl2和Ca(NO3)2·4H2 O为代表的潮解盐,易受北京四季温湿度变化的影响,潮解盐具有巨大破坏作用,从而使哈密恐龙骨骼化石风化区域孔隙率升高,孔隙增大,并且其内部充填物结构酥松且不均一,最终导致哈密恐龙骨骼化石酥粉破碎.该研究工作对哈密恐龙化石的异地保存及保护具有一定的科学指导意义.
Study on the Weathering of a Dinosaur Fossil From Hami,Xinjiang
The discovery of dinosaursfrom the Early Cretaceous Pterosaur Fauna in Xinjiang has increased the diversity of the fauna and provided new information for the phylogenetic evolution of dinosaurs,which is of great scientific significance.However,when the Hami dinosaur fossils were preserved off-site from their original burial environment,they showed severe weathering due to changes in the preservation environment.In order to better preserve,study,and display the Hami dinosaurfossils,this paper used a variety of analytical techniques to examine the Hami dinosaur fossils that have shownsignificant weathering and to analyze the causes of weathering and fragmentation of the fossils.X-ray diffraction(XRD)showed that the severely weathered area of the Hami dinosaur fossils was the cancellous part of the bone.The main mineral components were quartz and calcite,containing less apatite,feldspar and clay minerals.Quartz and feldspar are foreign clastic particles in the cancellous pores of the filled bone.Calcite is a cement formed in the later diagenesis or fossilization process,and a small amount of apatite is mainly from the bone.The results of ion chromatography(IC),Fourier transform infrared spectroscopy(FTIR),Raman spectroscopy(Raman)and scanning electron microscopy(SEM-EDS)showed that the soluble salts in the weathering area of dinosaur fossilswere mainly NaCl,CaCl2 and Ca(NO3)2·4H2O,and a small amount of CaSO4.The soluble salt content was as high as 2.63%,and the preliminary conclusion is that the high soluble salt content was the main cause of the severe weathering of fossils.The mercury intrusion test(MIP)results show that the porosity of the weathering area of dinosaur fossilis 21.272 2%,which is significantly increased compared with the porosity of 16.420 6%in the unweathered area.In addition,there are two kinds of pore size distribution in the weathering area of dinosaur fossils,with the sizes of 0.005~0.04 and 17.3~283.2 μm,respectively.Compared with the unweathered area,the weathering area produces microcracks,and the number of large pore-sized pores increases sharply.It is concluded that the fossils contain a large number of deliquescent salts represented by CaCl2 and Ca(NO3)2·4H2O,which are easily affected by the changes intemperature and humidity in Beijingduring four seasons recycles.The deliquescent salts have a great destructive effect,thus increasing the porosity of the weathered areas of the Hami dinosaur fossils and increasing the pores.The internal filling structure is flimsy and heterogeneous,which eventually leads to the fragmentation of the Hami dinosaur fossils.This research work is of scientific significance for preserving and protecting dinosaur fossils from Hami in ex situ.

Hami Pterosaur FaunaDinosaur fossilWeathering mechanismDeliquescent saltHami Xingjiang

韩向娜、代黎洋、蒋顺兴、汪筱林

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北京科技大学科技史与文化遗产研究院,北京 100083

中国科学院古脊椎动物与古人类研究所脊椎动物演化与人类起源重点实验室,北京 100044

中国科学院大学地球与行星科学学院,北京 100049

哈密翼龙动物群 恐龙骨骼化石 风化机理 潮解盐 新疆哈密

国家自然科学基金中国科学院青年创新促进会项目

422882012019075

2024

光谱学与光谱分析
中国光学学会

光谱学与光谱分析

CSTPCD北大核心
影响因子:0.897
ISSN:1000-0593
年,卷(期):2024.44(4)
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