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稀土发光纳米材料在手印显现中的应用进展

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自2000年起,研究人员陆续将一系列新型纳米材料应用到手印显现中,由此衍生了手印纳米显现技术.显现材料的推陈出新和显现方法的借鉴创新共同促进了手印纳米显现技术的迅速发展.近十年来,将稀土发光纳米材料应用于手印纳米显现技术的研究报道日益增多,已经逐渐成为该领域的研究热点之一.基于稀土发光纳米材料的手印显现技术具有对比度强、灵敏度高、选择性佳、毒害性低等突出优势,因此具备重要的理论研究价值和广阔的实践应用前景.目前,该研究领域的文献报道形式主要为研究类文章,鲜有涉及综述类文章.该文从显现材料的推陈出新和显现方法的借鉴创新两个方面综述了稀土发光纳米材料在手印显现中的研究进展.在显现材料的推陈出新方面,总结了基于稀土下转换发光纳米材料、稀土上转换发光纳米材料、复合型稀土发光纳米材料的手印显现应用;在显现方法的借鉴创新方面,总结了基于静电吸附原理、疏水作用原理、化学键合原理、适配体识别原理的手印显现方法.基于稀土发光纳米材料的手印显现研究呈现出如下发展趋势:显现材料由下转换发光材料向上转换发光材料发展,由单一发光材料向多重发光材料发展,由光致发光材料向功能复合材料发展;显现方法由非特异显现向靶向性显现发展,由痕迹物证的定性显现向遗留物质的定量检测发展,由物理显现向化学显现发展;显现效果由痕迹特征的宏观无损向生物物证的微观无损发展;显现操作由潜在毒害向绿色环保发展;显现评估由主观、片面、定性描述向客观、全面、定量分析发展.该综述对基于稀土发光纳米材料的手印显现技术提出了如下展望:首先是纳米材料的物理性质对手印显现效果的影响研究,其次是纳米材料的诸多性质对生物物证检验的影响研究,最后是显现原理的广泛借鉴与显现方法的深度开发研究.
Application Progress of Rare Earth Luminescent Nanomaterials in Fingerprint Development
Since 2000,various novel nanomaterials(NMs)have been successively applied in latent fingerprint(LP)development,resulting in the emergence of NM-based development of LPs.Due to the innovation of developing materials and methods,the NM-based development of LPs has mushroomed.In the past decade,more and more research on LP development using rare earth(RE)luminescent NMs has been reported,and this has gradually become one of the hot topics in this research field.The development of LPs based on RE luminescent NMs possesses prominent advantages such as strong contrast,high sensitivity,good selectivity,and low toxicity.Therefore,it has important theoretical research values and broad practical application prospects.Recently,most papers reported in this field were research articles,while the review articles were very limited.In this review,the application progress of LF development based on RE luminescent NMs was systematically summarized from two aspects:the renewal of developing materials and the innovation of developing methods.On the renewal of developing materials,this review emphasizes the LF development based on RE down-conversion(DC)luminescent NMs,RE up-conversion(UC)luminescent NMs,and RE multi-functional nanocomposites.On the innovation of developing methods,this review focuses on LF development based on electrostatic adsorption,hydrophobic effect,chemical bonding,and aptamer recognition strategies.The trends of LP development based on RE luminescent NMs can be summarized as follows:in terms of the developing materials,they involve in the transition from DC luminescent NMs to UC luminescent NMs,from single luminescent NMs to multiple luminescent NMs,from photoluminescent NMs to multi-functional nanocomposites;in terms of the developing methods,they involve in the transition from non-specific development to high targeting development,from qualitative development of trace evidence to quantitative detection of residual substances,from physical development to chemical development.In addition,developing results are involved in the transition from effective development of trace evidence to nondestructive detection of biological evidence;developing procedures are involved in the transition from potentially toxic operation to environmentally friendly operation;developing assessments are involved in the transition from subjective,uncomprehensive and qualitative description to objective,comprehensive and quantitative analysis.At the end of this review,we also put forward some prospects for LF development based on RE luminescent NMs,which should be further studied.

Fingerprint developmentLatent fingerprintNanomaterialsRare earthLuminescence

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中国政法大学刑事司法学院,北京 102249

手印显现 潜在手印 纳米材料 稀土 发光

国家自然科学基金国家社会科学基金青年项目辽宁省应用基础研究计划辽宁省教育厅科学研究经费项目

2120513923CFX0342023JH2/101300097LJKZ0068

2024

光谱学与光谱分析
中国光学学会

光谱学与光谱分析

CSTPCD北大核心
影响因子:0.897
ISSN:1000-0593
年,卷(期):2024.44(6)
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