首页|蓝珊瑚的光谱学特征和颜色成因

蓝珊瑚的光谱学特征和颜色成因

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蓝珊瑚是一种稀有的珊瑚品种,前人从生物学角度证实蓝珊瑚的致色与胆绿素有关,但没有相关光谱证据,且缺乏微观结构的研究,因此蓝珊瑚颜色成因的解释较为模糊.基于此,首先根据蓝珊瑚红外透射光谱4 000~2 000 cm-1的吸收带,表明蓝珊瑚中含有一定的有机物,并且有机物的含量与颜色深浅呈正相关性.蓝珊瑚蓝色区域拉曼光谱在1 616、1 542、1 459、1 356、1 314、1 264、1 167和970 cm-1处出现胆绿素的特征拉曼峰.蓝珊瑚紫外-可见光谱286、357和590 nm附近的吸收带也与胆绿素的吸收带相符,以上谱学特征说明蓝珊瑚蓝色与胆绿素有关.其次,蓝珊瑚的微形貌特征和成分分析表明,蓝珊瑚的珊瑚虫形成的孔洞纵向近似平行排列,并且孔洞分节叠加在一起.从孔洞内表面(骨刺状文石)→孔洞周围(片状文石)→孔洞之间(柱状文石),随着颜色由蓝色→白色,有机物的含量明显减少.结合前人研究结果,可以推测,孔洞之间白色文石由珊瑚虫外胚层分泌角质和石灰质形成,而在珊瑚虫死去后,内胚层和内胚层表面的刺细胞发生文石化,保留了珊瑚虫体内的有机物,而有机物中含有胆绿素,从而导致蓝珊瑚呈现蓝色.
Spectroscopic Characteristics and Color Origin of Blue Coral
Blue coral is a rare coral species.Previous studies have confirmed that the color of blue coral is related to biliverin from a biological point of view.Still,there is no relevant spectral evidence and a lack of microstructure studies,so the explanation for the color of blue coral is murky.Based on this,according to the absorption band of the infrared transmission spectrum of blue coral from 4 000 to 2 000 cm-1,this paper shows that blue coral contains certain organic matter,and the organic matter content is positively correlated with the color depth.The characteristic Raman peaks of biliverdin were found at 1 616,1 542,1 459,1 356,1 314,1 264,1 167 and 970 cm-1 in the blue region of blue coral.The absorption bands in the UV-VIS spectra of 286,357,and 590 nm are also consistent with the absorption bands of biliverdin.The above spectral characteristics indicate that the blue color of blue coral is related to biliverdin.Secondly,the micromorphologic characteristics and composition analysis of blue coral showed that the pores formed by blue coral polyps were approximately parallel longitudinally,and the holes were superimposed in segments.From the inner surface of the pores(spiniform aragonite)to the periphery of the pores(lamellar aragonite)to between the pores(columnar aragonite),the content of organic matter decreases significantly as the color changes from blue to white.Combined with the previous research results,it can be inferred that the exudation of keratin and calcareous substance from the ectoderm of polyps forms the white aragonite between the pores.After the polyps die,the endoderm and the nematocytes on the surface of the endoderm become fossilized,preserving the organic matter in the polyps,which contains biliverdin,causing the blue color of the blue coral.

Blue coralInfrared spectrumRaman spectrumUltraviolet-visible spectrumMicromorphologyColour

李雨田、于海燕、张可轩、柏鹤、张予烨

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桂林理工大学地球科学学院,广西桂林 541006

广西隐伏金属矿产勘查重点实验室,广西桂林 541006

蓝珊瑚 红外光谱 拉曼光谱 紫外-可见光谱 微形貌 颜色

国家自然科学基金项目广西科技基地和人才专项广西自然科学基金项目

42262006桂科AD220350352023GXNSFBA026273

2024

光谱学与光谱分析
中国光学学会

光谱学与光谱分析

CSTPCD北大核心
影响因子:0.897
ISSN:1000-0593
年,卷(期):2024.44(11)