首页|[NdPr2(C2O4)4.5(H2O)9]n配合物的合成、结构及性质研究

[NdPr2(C2O4)4.5(H2O)9]n配合物的合成、结构及性质研究

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通过水热法合成了 一种双核稀土配合物[NdPr2(C2O4)4.5(H2O)9]n,单晶结构解析表明配合物为双金属二维结构,属于单斜晶系,P21/n空间群.固体荧光分析说明配合物的最大激发波长为241 nm,最大发射波长为391 nm.配合物发紫色荧光,其电极作为传感器检测多巴胺,线性检测范围为16.6~280 μmol/L.配合物具有相对较宽的线性检测范围,材料抗干扰能力强,可用于对多巴胺的检测.
Hydrothermal Synthesis,Structure and Performance of[NdPr2(C2O4)4.5(H2O)9]n
A binuclear rare earth complex[NdPr2(C2O4)4.5(H2O)9]n was synthesized by hydrothermal method.The single crystal structure analysis shows that the complex has a bimetallic two-dimensional structure and belongs to the monoclinic system,with a P21/n space group.Solid state fluorescence analysis shows that the maximum excitation wavelength of the complex is 241 nm,and the maximum emission wavelength is 391 nm.The complex emits purple fluorescence,and its electrode serves as a sensor for detecting dopamine,with a linear detection range of 16.6~280 μmol/L.The complex has a relatively wide linear detection range and strong anti-interference ability of the material,making it suitable for the detection of dopamine.

binuclear rare earth complexcrystal structurefluorescence propertiesdopamine

江涛、张雅文、徐国茂、林泽如、姚舒婷、简映妍

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广东第二师范学院化学与材料科学学院,广东广州 510303

双核稀土配合物 晶体结构 荧光性质 多巴胺

2024

甘肃高师学报
甘肃民族师范学院 定西师范高等专科学校,陇南师范高等专科学校 兰州城市学院

甘肃高师学报

CHSSCD
影响因子:0.173
ISSN:1008-9020
年,卷(期):2024.29(2)