高师理科学刊2024,Vol.44Issue(8) :61-64.DOI:10.3969/j.issn.1007-9831.2024.08.010

基于MOF衍生的In掺杂ZnO纳米材料对NO2的气敏性能

Gas sensitivity performance of In-doped ZnO nanomaterials derived from MOF towards NO2

王思博 赵振龙 贾丽华
高师理科学刊2024,Vol.44Issue(8) :61-64.DOI:10.3969/j.issn.1007-9831.2024.08.010

基于MOF衍生的In掺杂ZnO纳米材料对NO2的气敏性能

Gas sensitivity performance of In-doped ZnO nanomaterials derived from MOF towards NO2

王思博 1赵振龙 1贾丽华1
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作者信息

  • 1. 齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔市 161006
  • 折叠

摘要

以硝酸锌和二甲基咪唑为原料,采用溶剂热法制备了ZIF-8,通过掺杂不同含量的In3+离子,制备了基于MOF衍生的In3+掺杂ZnO复合纳米材料.采用X射线衍射(XRD)、X射线光电子能谱测试(XPS)、氮气吸附-脱附等方法对合成材料进行了结构表征.研究了In3+离子掺杂对材料的结构形貌和性能的影响.掺杂In3+的ZnO纳米复合材料对二氧化氮气敏性能明显提高,160℃工作温度下,对1 mg/L的二氧化氮的响应值从75提高到350,最低检测线为1 μg/L.所给的纳米材料制备方法简单,气敏性能优异,为NO2气体的高灵敏检测提供了潜在方法.

Abstract

Zinc nitrate and dimethyl imidazole were used as raw materials to prepare ZIF-8 by the solvothermal method.In-doped ZnO nanomaterials derived from MOF were synthesized by doping In3+ions.The synthesized samples were characterized by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),nitrogen adsorption-desorption,etc.The influence of In3+ion doping on the structure,morphology,and properties of materials has been studied.The sensor based on the ZnO nanocomposite doped In+shows significantly improved sensitivity to NO2,with the response value increasing from 75 to 350 for 1 mg/L of NO2 at an operating temperature of 160℃,and the lowest detection limit is 1 μg/L.The preparation method of nanomaterials is simple and has excellent gas sensitive properties,which provides an potential way for highly sensitive detection of NO2 gas.

关键词

金属有机框架/ZnO/传感器/气敏/NO2

Key words

metal-organic frameworks/ZnO/sensor/gas-sensitive/NO2

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出版年

2024
高师理科学刊
齐齐哈尔大学

高师理科学刊

影响因子:0.351
ISSN:1007-9831
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