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气基竖炉直接还原数值模拟分析

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针对气基竖炉直接还原过程无法直接观察还原反应运行程度的难点,基于三界面未反应核模型,在忽略模型球团内部温度及假设球团还原反应的热效应完全发生在固相的条件下,建立了气基竖炉直接还原模型,对铁氧化物价态转变进行了数值模拟和验证.结果表明,由于所建立的气固模型包含3个界面,随着铁氧化物的逐级还原,每个界面的反应半径最终趋于0,而还原反应速率随着竖炉深度的增加呈现出先升高后降低的趋势.球团在竖炉内下降到3 m深度时,出现半径为15 mm的FeO反应界面,此时球团还原率约为28%.随着球团继续在竖炉内下行约2 m到达5 m的深度时,Fe3O4的界面半径减小为0,此时铁氧化物完全转变成了浮氏体形态,球团还原率约为34%.通过改变不同的工艺参数进行模拟可以发现,还原球团金属化率和还原率随着气体温度的升高而增大.当气体温度以50 ℃、还原气体流量以5 040 m3/h梯度增大时,其对应的球团金属化率分别增大8%和4%左右.相比之下,球团金属化率受下料速度的影响远超过气体温度和还原气体流量,具体表现为,当下料速度增大0.02 t/h时,金属化率降低约0.07%.而当球团粒度减小时,金属化率会表现增大的趋势,球团粒度减小1 mm,球团金属化率增大2.23%.
Numerical simulation analysis of direct reduction of gas-based shaft furnace
Aiming at the difficulty that the operation degree of the reduction reaction cannot be directly observed dur-ing the direct reduction process of the gas-based shaft furnace,based on the three-interface unreacted nuclear model,a direct reduction model of the gas-based shaft furnace is established under the condition of ignoring the internal tem-perature of the model pellet and assuming that the thermal effect of the pellet reduction reaction completely occurs in the solid phase,and the valence state transformation of iron oxide is numerically simulated and verified.The results show that since the established gas-solid model contains three interfaces,the reaction radius of each interface eventu-ally tends to zero with the stepwise reduction of iron oxides,and the reduction reaction rate increases first and then decreases with the increase of shaft furnace depth.When the pellets descend to a depth of 3 m in the shaft furnace,a FeO reaction interface with a radius of 15 mm appears,where the pellet reduction rate is about 28%.As the pel-lets continue to descend about 2 m in the shaft furnace to a depth of 5 m,the radius of the interface of Fe3O4 decrea-ses to 0,at which point the iron oxide completely transforms into the floatite form,and the pellet reduction rate is a-bout 34%.By changing different process parameters for simulation,it can be found that the metallization rate and reduction rate of the reducing pellet increase with the increase of gas temperature.When the gas temperature increa-ses at 50 ℃ and the reducing gas flow rate increases at a gradient of 5 040 m3/h,the corresponding pellet metalliza-tion rate increases by about 8%and 4%,respectively.In contrast,the metallization rate of the pellets is much more affected by the cutting speed than the gas temperature and reducing gas flow,which is manifested as follows:when the cutting speed increases by 0.02 t/h,the metallization rate decreases by about 0.07%.When the pellet size de-creases,the metallization rate will show an increasing trend,and the pellet size decreases by 1 mm,and the pellet metallization rate increases by 2.23%.

gas based shaft furnacegas based methoddirect reducednumerical simulationreduction ratemetal-lization rate

白晨晨、师学峰、王明阳、于浩、胡长庆、韩涛

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华北理工大学冶金与能源学院,河北唐山 063210

气基竖炉 气基法 直接还原 数值模拟 还原率 金属化率

河北省高等学校科学技术研究资助项目

ZD2020116

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(1)
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