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矿焦耦合冶金性能试验及评价方法

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铁矿石和焦炭在高炉内各区域的反应及特性是影响高炉炼铁效率和产量的重要因素,准确评价矿焦质量备受炼铁工作者关注.评价矿或焦冶金性能的试验方法及指标迅速发展,且部分方法已标准化,包括铁矿石软熔性能和焦炭反应性及反应后强度的试验方法等被钢铁企业广泛采用.然而,通过现有评价矿或焦冶金性能的方法及指标推算高炉技术经济指标尚存难度.原因可能在于没有充分模拟矿焦在高炉中历经还原、溶损、软化-熔融全过程的相互作用,无法对矿焦关联行为及特性进行赋值并构建评价矿焦相互作用的指标体系.因此,提出了采用焦-矿-焦分层试料,模拟矿焦在高炉内还原、溶损、软化和熔融之间关联行为及特性的荷重-热重-气体分析联动试验装置,进行矿焦耦合性能试验及评价的方法(Qisunny法).变矿或变焦试料的试验结果表明,矿焦耦合冶金性能按间接还原区、间接还原和直接还原及软化区、熔融直接还原和滴落直接还原4个区域依次演变;性能评价指标包括各区域的温度及区间、间接和直接还原度、总间接还原度、熔融区透气性特征值、上层焦炭溶损率及溶损后强度等;焦炭的溶损反应主要发生在熔融区,上层焦炭溶损率与传统指标焦炭反应性指数相近,但其反应后强度明显高于传统指标焦炭反应后强度指数.该方法为评价矿焦冶金性能之间的相互作用、优化矿焦炉料结构提供了一种全新的选择.
A test and evaluation method of ore and coke coupling metallurgical properties
The reaction and characteristics of iron ore and coke in various areas of the blast furnace(BF)are impor-tant factors affecting the efficiency and yield of BF ironmaking,so that accurate evaluation of the quality of ore and coke has been arousing interests from ironmakers.The testing methods and indexes for evaluating the metallurgical properties of ore or coke have rapidly developed,and some methods have been standardized,including the method for determination of iron ore softening-melting performance under load and the determination of coke reactivity index and coke strength after reaction,etc.The methods have been widely adopted by iron and steel enterprises.Howev-er,it is still difficult to calculate the technical-economic indexes of BF from on the experimental results based on cur-rent testing methods and indexes.This may be due to insufficient simulation on the interaction between ore and coke through the entire process of reduction,solution loss,softening and melting in BF.Assigning values to the correla-ted behaviours and characteristics of ore and coke and constructing an indicator system to evaluate the interaction be-tween them could not be achieved.Therefore,a test device and evaluation methodology(Qisunny method)have been invented,which deploy samples with coke-ores-coke layer structure in the crucible integrating the reduction un-der the load-thermogravimetric-gas analysis to simulate coupling ores and coke behaviours and properties,such as i-ron ore reduction,coke solution loss,burden softening,melting and dropping.The device and methodology can conduct coke and ore coupling behaviours and properties test and evaluate its coupling performance.The test results of changing burden structure and coke type showed that coupling coke and ore metallurgical performance evolved with different zones with distinct boundary in an order from indirect reduction zone to indirect and direction reduction co-existing and softening zone,to smelting direct reduction zone and to dripping direct reduction zone.The perform-ance evaluation parameters included the temperature and the temperature interval of different zones,the indirect and direct reduction rate,the total reduction rate,the permeability parameters in melting zone,the solution loss rate and strength after dissolution of the top layer coke.The solution loss reaction of coke mainly taken place in the melting zone.The solution loss rate of the upper layer coke was close to the traditional coke reactivity index while its strength after dissolution was higher than the traditional coke strength index after reaction.The method can provide a totally new option for evaluating coupling coke-ore performances and optimising burden structure.

blast furnaceiron orecokecoupling metallurgical propertiesevaluation method

汪琦、宋阳升、李廷乐、李哲熙、TIM Evans

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辽宁科技大学材料与冶金学院,辽宁鞍山 114051

力拓集团,西澳大利亚州 珀斯6000

高炉 铁矿石 焦炭 耦合冶金性能 评价方法

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(2)
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