首页|铈对Fe-28Mn-10Al-1C低密度钢中非金属夹杂物的影响

铈对Fe-28Mn-10Al-1C低密度钢中非金属夹杂物的影响

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为了研究稀土铈对Fe-28Mn-10Al-1C低密度钢中非金属夹杂物的影响机理,通过扫描电子显微镜(SEM)、能谱分析仪(EDS)及Image J软件对比分析了稀土处理前后夹杂物的形貌、成分、尺寸和数量,并基于热力学计算阐明了稀土铈对夹杂物的改性机理.研究结果表明,低密度钢中典型夹杂物为AlN和AlN-MnS复合夹杂物,钢中AlN夹杂物较多,尺寸较大,平均直径为3.64 μm;向低密度钢中添加(质量分数)0.001 9%铈后,夹杂物以球状AlN-Ce2S3、AlN-Ce2S3-MnS、AlN-MnS复合夹杂物和单一AlN夹杂物为主,整体夹杂物数量最少,夹杂物平均直径及长宽比降低,平均直径为3.08 μm;向低密度钢中添加(质量分数)0.013%铈后,夹杂物则以球状Ce2S3、附着态AlN-Ce2S3和单一AlN夹杂物为主,夹杂物数量异常升高,1~4 μm夹杂物所占比例较大,平均直径为2.52 μm.稀土处理可有效细化夹杂物尺寸并改善大尺寸氮化物和硫化物夹杂的形貌特征,未检测到单一MnS及Al2O3夹杂物.此外,通过FactStage 8.0热力学计算软件分析了稀土铈对Fe-28Mn-10Al-1C低密度钢中AlN、MnS夹杂物影响规律、稀土夹杂物的析出行为及演变过程,计算表明,AlN在冶炼温度下即可形成,MnS倾向于异质形核,生成AlN-MnS复合夹杂物;加入(质量分数)0.001 9%铈后,Ce2S3 以AlN为核心析出形成AlN-Ce2S3,钢中硫含量降低,抑制了MnS的析出;加入(质量分数)0.013%铈后,析出大量小尺寸Ce2S3夹杂物.
Effect of cerium on non-metallic inclusions in Fe-28Mn-10Al-1C lightweight steel
To study the effect of rare-earth Ce on the formation of inclusions in Fe-28Mn-10Al-1C lightweight steels,the morphology,composition,size and number of inclusions in Fe-28Mn-10Al-1C lightweight steels before and after rare earth addition was analyzed by SEM-EDS and Image J analysis software.The results show that the typical inclusions were mainly AlN and AlN-MnS complex inclusions in the current lightweight steel,and a large number of single AlN inclusion was with an average size of 3.64 μm.When 0.001 9%Ce(mass percent)was added,the main inclusions were spherical AlN-Ce2S3,AlN-Ce2S3-MnS,AlN-MnS complex inclusions and single AlN inclusions,the total number of inclusions was the least,and the average diameter and aspect ratio of the inclu-sions were decreased.The size distribution of inclusion was the most uniform and the average size was 3.08 μm.When 0.013%Ce(mass percent)was added,the main inclusions were spherical Ce2S3,AlN-Ce2S3 and single AlN inclusions,the number of inclusions increased abnormally,and the inclusions was with an average size of 2.52 μm.The rare earth treatment can effectively refine the size of inclusions and improve the morphology of Al2O3 and MnS inclusions with a large size,and no single Al2O3 and MnS inclusions were detected in the steel.In addition,the pre-cipitation behavior and evolution process of rare earth Ce on AlN,MnS inclusions and the formation mechanism of rare earth inclusions in Fe-28Mn-10Al-1C lightweight steel were calculated by FactStage8.0.The calculation results show that AlN could be formed during the smelting process,and MnS inclusion trend to heterogeneous nucle-ation.After the addition of 0.001 9%Ce(mass percent),Ce2S3 inclusion precipitated on the surface of AlN and pre-vented the formation of MnS inclusion.With the addition of 0.013%Ce(mass percent),a large number of fine Ce2S3 precipitated in the lightweight steel.

non-metallic inclusionlightweight steelrare earth modificationthermodynamic calculationFe-Mn-Al-C

周杰、朱航宇、王蓝卿、潘雨桐、袁文达

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武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室, 湖北 武汉 430081

武汉科技大学钢铁冶金新工艺湖北省重点实验室, 湖北 武汉 430081

非金属夹杂物 低密度钢 稀土处理 热力学计算 Fe-Mn-Al-C

国家自然科学基金国家自然科学基金

5207419952374341

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(3)
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