首页|G30Cr15Mo1N高氮马氏体钢的连续冷却相变与强化机制

G30Cr15Mo1N高氮马氏体钢的连续冷却相变与强化机制

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利用Formastor-F2全自动相变仪测量G30Cr15Mo1N钢的CCT曲线,分析在连续冷却转变过程中高氮钢的组织变化和相转变规律,以指导热处理工艺的制定.另外,还通过XRD、SEM、EDS和TEM等分析方法研究了G30Cr15Mo1N钢在不同回火工艺下组织和力学性能演变,分析细晶强化、固溶强化、位错强化和析出强化对G30Cr15Mo1N钢屈服强度的贡献情况.结果表明,试验钢在实际升温中的Ac1和Ac3温度分别为840和870℃,片层珠光体的转变温度区间为600~700℃,珠光体形成的最快冷速为1℃/s.试验钢在较低温度(≤500℃)回火后微观组织为碳氮化物+回火马氏体+残余奥氏体,整体上保持较高的屈服强度和抗拉强度,分别大于 1 750和2 050 MPa,而伸长率低于3%;在600℃回火后马氏体发生回复再结晶,马氏体板条形貌基本消失,并在TEM试验中观察到尺寸在20~80 nm的短棒状Cr2(C,N)析出物,这导致高氮钢的强度大幅度下降而塑性得到充分恢复.在150℃回火时,G30Cr15Mo1N钢的屈服强度主要来源于很高的固溶强化和位错强化,其中固溶强化占主要作用;在500℃回火后,位错强化和固溶强化分别降低83.7和249.3 MPa,而析出强化显著增强并产生二次硬化,其主要来源是较高比例尺寸小于10 nm析出相.而当回火温度高达600℃时,固溶强化、位错强化、第二相强化均大幅度下降,且对屈服强度的贡献较为均衡,共同起到了重要的强化作用.
Continuous cooling transformation and strengthening mechanism of G30Cr15Mo1N high nitrogen martensite steel
The CCT curve of G30Cr15Mo1N steel was measured by Formastor-F2 automatic phase transformation instrument,and the microstructure change and phase transformation of high nitrogen steel in the process of continu-ous cooling transformation were analyzed to guide the formulation of heat treatment process.In addition,the micro-structure and mechanical properties of G30Cr15Mo1N steel at different tempering temperatures were studied by XRD,SEM,EDS and TEM characterization methods,and the strength contributions of grain size,solid solution,dis-location and precipitation to the yield strength of G30Cr15Mo1N steel was analyzed.The results show that the Ac1 and Ac3 temperatures of the experimental steel are 840 and 870℃respectively,the temperature range of lamellar pearlite transformation is 600-700 ℃,and the fastest cooling rate of pearlite formation is 1℃/s;after tempering at a lower temperature(≤500℃),the microstructure of the experimental steel is composed of carbon nitride,tempered martensite,and remained austenite,and maintains high yield strength and tensile strength,exceeding 1 750 and 2 050 MPa,respectively,while the elongation is less than 3%;after tempering at 600℃,the martensite recovers and recrys-tallizes,and the strip shape of martensite plate basically disappears.A short rod like Cr2(C,N)precipitate with the size of 20-80 nm was observed in the TEM,which led to a significant decrease in the strength of high nitrogen steel and a full recovery of plasticity.When tempered at 150℃,the yield strength of G30Cr15Mo1N steel mainly comes from high solid solution and dislocation strengthening,among which solid solution strengthening plays a major role;after tempering at 500 ℃,the strength contributions of dislocation and solid solution respectively decrease 83.7 and 249.3 MPa,the main source of the significant secondary hardening effect is a higher proportion of precipitates with a size smaller than 10 nm.When the tempering temperature is as high as 600 ℃,the solid solution,dislocation,and sec-ond phase strengthening all decrease significantly,and the contribution to the yield strength is relatively balanced,which together play an important role in strengthening.

high nitrogen martensite steelcontinuous cooling transformationtemperingmicrostructurestrength-ening mechanism

李波、陈豪、胡忠会、贾忠宁、陈泽军、曹文全

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中国航空工业集团公司第一飞机设计研究院,陕西 西安 710089

重庆大学材料科学与工程学院,重庆 400044

钢铁研究总院有限公司特殊钢研究院,北京 100081

高氮马氏体钢 连续冷却转变 回火 显微组织 强化机制

国家重点研发计划国家自然科学基金面上项目

2016YFB030010151871062

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(5)
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