首页|燃料电池双极板结构激光增材制造及表面精整加工

燃料电池双极板结构激光增材制造及表面精整加工

Optimization of polishing process for bipolar plates in fuel cells manufactured via laser additive manufacturing

扫码查看
质子交换膜燃料电池双极板异形截面微流道制造成形存在挑战,且表面粗糙度对其性能与寿命造成重要影响.激光粉末床熔融(laser powder bed fusion,LPBF)技术得益于成形自由度高、可实现复杂结构成形等特点,在解决该复杂微流道成形问题方面具有显著优势,且磨粒流加工可实现复杂流道的高效精抛光.采用LPBF技术成形了316L不锈钢质子交换膜燃料电池双极板异形截面微流道结构,获得了优化的激光工艺(激光功率为150 W,扫描速度为800 mm/s,扫描间距为50 μm),该工艺下成形试样致密度为99.5%.自主研发设计了磨粒流抛光设备及夹具,对优化工艺下LPBF成形的异形截面微流道进行了抛光工艺优化,基于光镜、激光共聚焦和扫描电子显微镜等试验手段,研究了不同抛光压力对LPBF成形质子交换膜燃料电池双极板异形截面微流道成形精度、表面粗糙度及显微组织的影响规律,获得了最佳磨粒流抛光工艺(抛光压力为 9 MPa、抛光时间为 90 min、磨粒粒径为0.037 5 mm).结果表明,随着抛光压力增大,微流道内壁质量得到了有效提升且沿微流道长度方向的抛光不均现象明显改善,抛光压力为9~11 MPa时,成形构件表面粗糙度低至2.43~3.57 μm,改善量可达77.9%~85.7%.流道结构顶部硬度最小,变化量最大,与悬垂位置的致密度及显微组织有关.其中抛光压力为9 MPa时,中间及出口处的设计总偏差量最小,分别为61 μm和82 μm.揭示了磨粒流抛光LPBF成形燃料电池双极板异形截面微流道的机制,以期为LPBF成形复杂结构的表面精整工作提供参考.
Manufacturing complex-shaped microchannels on proton exchange membrane fuel cell(PEMFC)bipolar plates poses challenges,and surface roughness significantly affects their performance and lifespan.Laser powder bed fusion(LPBF),with its high degree of formability and capability to produce complex structures,offers significant advantages in forming these intricate microchannels.Moreover,abrasive flow machining enables efficient polishing of complex channels.LPBF was employed to fabricate 316L stainless steel PEMFC bipolar plates with complex-shaped microchannel structures.Optimized laser parameters(laser power of 150 W,scanning speed of 800 mm/s,and scanning spacing of 50 μm)resulted in a sample density of 99.5%.A custom abrasive flow polishing device and fixtures were developed to optimize the polishing process for LPBF-fabricated microchannels.Through experimen-tal techniques including optical microscopy,laser confocal microscopy,and scanning electron microscopy,the effects of different polishing pressures on the dimensional accuracy,surface roughness,and microstructure of LPBF-fabricated PEMFC bipolar plates with complex-shaped microchannels were investigated.Optimal abrasive flow pol-ishing parameters(polishing pressure of 9 MPa,polishing time of 90 min,and abrasive particle size of 0.037 5 mm)were determined.Increasing the polishing pressure effectively enhanced the quality of the microchannel inner walls and significantly improved the unevenness along the length of the microchannels.At polishing pressures of 9-11 MPa,surface roughness of the fabricated components reduced to 2.43-3.57 μm,with an improvement of up to 77.9%-85.7%.The top of the channel structure exhibited the lowest hardness and the most significant variation,correlating with the density and microstructure at the hanging position.Specifically,at a polishing pressure of 9 MPa,the total design deviation at the midpoint and exit of the microchannels was minimized,measuring 61 μm and 82 μm,respectively.The mechanism of abrasive flow polishing for LPBF-formed PEMFC bipolar plates with complex-shaped microchannels was elucidated,aiming to provide insights into surface finishing for LPBF-formed intricate structures.

laser additive manufacturingabrasive flow machiningfuel cellmicrochannelsurface finishingpol-ishing pressure

张万里、林开杰、陕俊豪、许勇、黄广靖、孙婧佳、顾冬冬

展开 >

南京航空航天大学材料科学与技术学院,江苏 南京 210000

江苏省高性能构件激光增材制造工程研究中心,江苏 南京 210016

激光增材制造 磨粒流 燃料电池 微流道 表面精整 抛光压力

国家重点研发计划国防基础科研项目江苏省重点研发计划江苏省重点研发计划

2021YFB1715400JCKY2020605C007BE2022069BE2022069-1

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(6)
  • 1
  • 9