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低温冶金理论、技术及未来发展

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经过21年的研发,初步形成了低温冶炼理论体系,低温冶炼新装备、新工艺试验工程、生产线建设持续推进.与高温冶金相比,低温冶金过程耗碳少、化学热及物理热需求少.通过煤种、粒度、温度等工艺参数的改变,可控制自产煤气中CO2含量.低温还原过程热负荷低于高温还原,通过上下加热为主、四周协同加热强化低温传热.提出了冷压球团-低温还原-电炉熔分钢铁冶炼新工艺流程,研制了低温还原反应新装备,开发了自产煤气低成本100%循环利用、低温还原炉废热梯级利用、抑制磷、硅还原等技术,实现了从原料预处理到炼钢过程的连续化(准连续化)生产,省去了烧结、焦化、氧化球团等炼铁工序和部分炼钢工序,实现了大幅度降低了冶炼能耗、煤耗、二氧化碳排放量以及炼钢过程的氧气和生石灰消耗.研制和建设了 5万t/a级的低温还原炼铁新装备工业试验工程,打通了工艺流程、验证了冶炼各个装备,创造了吨金属煤耗300 kg的煤基炼铁流程新记录,得到低磷、低硫、低碳钢水.低温冶炼技术还在金属铁粉制备、含锌粉尘制备金属锌锭、钒钛磁铁矿、钛铁精矿粉、高磷铁矿、废旧电池回收、废轮胎回收领域等多个领域应用.利用可再生能源生物质或生物炭逐步替代煤粉进行低温还原,有望实现冶炼过程的近零碳排放,为冶炼"碳中和"提供一种有效的低成本可实施途径.
Theory,technology and future development of low temperature metallurgy
After 21 years of research and development,a theoretical system of low-temperature metallurgy has been initially formed,and the development of new low-temperature smelting equipment,new process test projects,and production line design and construction are continuing to advance.Compared with the high temperature reduction process,the low temperature reduction process consumes less carbon and requires less chemical and physical heat.The CO2 content in self-produced gas can be controlled by changing the process parameters such as coal type,par-ticle size and temperature.The heat load of low temperature reduction process is lower than that of high temperature reduction process,and the low temperature heat transfer is strengthened by the upper and lower heating and the sur-rounding collaborative heating.The new steel smelting process of"cold briquette-low temperature reduction-electric furnace melting"was put forward,the new equipment of low temperature reduction reaction was developed,and the technology of low cost 100%recycling of self-produced gas,step utilization of low temperature reduction furnace waste heat,inhibition of phosphorus and silicon reduction was developed,and the continuous(quasi-continuous)production from raw material pretreatment to steelmaking was realized.The iron-making processes such as sinter-ing,coking,oxidizing pellets and some steelmaking processes are eliminated,and the smelting energy consumption,coal consumption,carbon dioxide emissions,as well as the oxygen and quicklime consumption in the steelmaking process are greatly reduced.The new low-temperature reduction ironmaking equipment with a capacity of 50 000 t/a iron making has been successfully developed,the industrial test demonstration project has been constructed and the integration of low-temperature metallurgical process flow has been achieved,the reliability of various smelting equip-ment has been inspected,a new record of coal based ironmaking process with a coal consumption of 300 kg per ton of metal has been created and low phosphorus,low sulfur and low carbon liquid steel has been obtained.Low-temperature metallurgy technology is also used in the preparation of metal iron powder,zinc dust preparation of metal zinc ingot,vanadium titanium magnetite,titanium iron concentrate powder,high phosphorus iron ore,waste battery recycling,waste tire recycling and other fields.The use of renewable energy biomass or biochar to gradually replace pulverized coal for low temperature reduction is expected to achieve near-zero carbon emissions in the smelt-ing process,and provide an effective and low-cost way to"carbon neutrality"in direct reduction iron making.

low temperature metallurgyironmakingsteelmakingcarbon neutralbiomassnew technology

郭培民、王磊、孔令兵、赵沛

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中国钢研科技集团有限公司氢冶金中心,北京 100081

钢铁研究总院有限公司先进钢铁流程及材料国家重点实验室,北京 100081

低温冶金 炼铁 炼钢 碳中和 生物质 新工艺

国家自然科学基金资助项目国家自然科学基金资助项目山西省科技重大专项计划"揭榜挂帅"资助项目

5220433952104297202201050201011

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(9)
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