首页|氢冶金炼钢技术的研究现状与展望

氢冶金炼钢技术的研究现状与展望

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提出了"氢气炼钢"代替"氧气炼钢"的观点,对"氢气炼钢"的研究现状进行了总结和评价.氢冶金炼钢在节能降耗和改善产品质量方面具有独特优势.一方面,"氢"具有高效熔炼作用,能够有效降低炼钢能耗.等离子体态的"氢"具有高温、高热导率的优势,可作为高效热源实现炉料熔化与钢液加热,在电弧炉、转炉以及中间包等炼钢设备中得到初步应用.喷吹气态"氢"能够加速成分和温度均匀,且氢气泡运动能粘附和加快其他非金属夹杂物上浮;同时与钢液中的氧等反应释放大量热量,改善了熔池反应的热力学与动力学条件.此外,"氢"通过营造还原性气氛,抑制氧化,降低Cr、Mn等合金元素的损耗.另一方面,"氢"具有无污染精炼的作用,能够显著提高钢液洁净度.基于"氢"的高活性和高还原性,"氢"能够有效去除钢中O、C、N、S和P等杂质元素,尤其是等离子态"氢",可直接与杂质元素反应生成H2O、CH4、NH3、H2S和PH3等极易挥发去除的气体产物,避免非金属夹杂物形成,实现"零夹杂物"的高效高洁净度炼钢.因而,发展以"氢"代"碳"的氢冶金新一代绿色近零碳"零夹杂物"无污染钢铁冶金流程,将加速钢铁工业绿色高质量可持续发展,助力中国实施"双碳"与"制造强国"战略.
Research status and prospect of hydrogen metallurgy steelmaking technology
The idea of"hydrogen steelmaking"replaces"oxygen steelmaking"is put forward,and the research status of"hydrogen steelmaking"is summarized and evaluated.Hydrogen metallurgy steelmaking has unique advantages in energy saving,consumption reduction and product quality improvement.On the one hand,hydrogen has a highly effi-cient melting effect,which can effectively reduce the energy consumption of steelmaking."Hydrogen"in plasma state has the advantages of high temperature and high thermal conductivity,which can be used as a highly efficient heat source to realize the melting of charge and heating of steel,and has been applied in steelmaking processes such as EAF,converter and tundish.Blowing gaseous"hydrogen"can accelerate the composition and temperature unifor-mity,and the movement of hydrogen bubbles can be adhered to and accelerate the floating of other non-metallic inclu-sions.At the same time,hydrogen reacts with oxygen in the liquid steel to release a large amount of heat,which improves the thermodynamic and kinetic conditions of the melt pool reaction.In addition,"hydrogen"can inhibit oxi-dation and reduce the loss of Cr,Mn and other alloying elements by creating a reducing atmosphere.On the other hand,"hydrogen"has a non-polluting refining effect that significantly improves the cleanliness of the steel.Based on the high activity and high reducibility of"hydrogen","hydrogen"can effectively remove impurity elements such as O,C,N,S and P in steel,especially"hydrogen"in plasma state,which can directly react with the impurity elements to generate H2O,CH4,NH3,H2S and PH3 and other gaseous products that are easy to be volatilized and removed,so as to avoid the formation of non-metallic inclusions,and to realize the highly efficient and high-cleanliness steelmaking with"zero inclusions".Therefore,the development of a new generation of green,near-zero carbon,"zero inclusion"and pollution-free steelmaking process using"hydrogen"instead of"carbon"will accelerate the green,high-quality,and sustainable development of the steel industry and support China implement the strategy of"dual-carbon"and"manufacturing power".

hydrogen metallurgysteelmakinghydrogen plasmameltingrefininggreen and low-carbon

姜周华、杨策、朱红春、陆泓彬

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东北大学冶金学院,辽宁沈阳 110819

东北大学轧制技术及连轧自动化国家重点实验室,辽宁沈阳 110819

氢冶金 炼钢 氢等离子体 熔炼 精炼 绿色低碳

国家重点研发计划资助项目中国宝武低碳冶金创新基金资助项目中央高校基本科研业务专项资金资助项目

2022YFC3901403BWLCF202211N2225046

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(9)
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