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含硫易切削钢的钙处理工艺研究与实践

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含硫易切削钢由于良好的力学性能和切削性能被广泛应用于汽车制造、机械制造、船舶建造等行业.随着近年来基础建设、乘用车和航运领域的发展,含硫易切削钢的产量和质量要求也不断提高.通常采用钙处理的方法来调控钢水中的夹杂物,而含硫钢的含硫特性对冶炼和连铸过程中的钢水洁净度和钢水的可浇性有严重的负面影响,因此,如何制定合理的钙处理工艺对于提高易切削钢的可浇性具有重要意义.系统研究了喂入钙线和硫线的加入时机、时间间隔和钙线加入量等因素对钢水洁净度和水口结瘤的影响规律,分析了含硫易切削钢水口结瘤的主要原因.研究表明,钙处理后钢液中会产生表面为CaS而芯部为Al2O3的夹杂物,这种夹杂物在水口内壁的不断附着沉积是导致水口堵塞的主要原因.在铝质量分数为0.03%的钢水中,当硫质量分数超过 0.015%时,易产生高熔点夹杂物而恶化钢水可浇性.对于转炉出钢量为140 t的45S含硫易切削钢,将硫线分别在LF和RH后喂入、延长钙线和硫线间的喂入间隔时间至10 min以上、减少钙线总喂入量至100 m以下均能有效减少钢液中CaS·Al2O3夹杂物数量,并且将45S钢种的连浇炉数提升至15炉以上.研究为优化含硫易切削钢的钙处理工艺提供了理论依据,有助于提高生产效率和产品质量,对推动机械、交通等领域用含硫易切削钢的应用和发展具有重要意义.未来将针对如何控制含硫钢种的夹杂物数量和形态、夹杂物在轧后对钢板质量的影响以及如何减少钙的添加量进行深入研究.
Research and practice of calcium treatment processes in sulfur-containing free-cutting steel
Due to its good mechanical properties and cutting performance,sulfur-containing free-cutting steel is widely used in industries such as automotive manufacturing,machinery manufacturing,and shipbuilding industry.With the development in the fields of infrastructure,passenger vehicles,and maritime transportation in recent years,the production volume and quality requirements of sulfur-containing free-cutting steel have also increased.The method of calcium treatment is usually used to regulate the inclusions in the steel.However,the sulfur-containing characteristics of sulfur-containing steel have a significant negative effect on the cleanliness and castability of the steel during the smelting and casting processes.Therefore,establishing a reasonable calcium treatment pro-cess is of great importance for improving the castability of sulfur-containing free-cutting steel.The effects of factors such as the timing of sulfur wire addition,the time interval between feeding calcium wire and sulfur wire,and the amount of calcium wire added on the cleanliness of the steel and the clogging of nozzle were systematically investi-gated,analyzing the main reasons for the nozzle clogging in sulfur-containing free-cutting steel.The research shows that inclusions with CaS on the surface and Al2O3 in the core are generated in the steel after feeding sulfur wire and calcium treatment.The continuous deposition and adhesion of these inclusions on the inner wall of the nozzle are the main cause of nozzle clogging.In steel with w([Al])=0.03%,when w([S])exceeds 0.015%,it is prone to the formation of high melting point inclusions,deteriorating the castability of the steel.For 140 t of 45S sulfur-containing free-cutting steel,feeding the sulfur wire separately after LF and RH,extending the feeding interval between calcium wire and sulfur wire to over 10 minutes,and reducing the total feeding amount of calcium wire to below 100 m can effectively reduce the quantity of CaS·Al2O3 inclusions in the steel.This can increase the number of continuous casting heats for 45S steel to over 15 heats.It provides a theoretical basis for optimizing the calcium treatment process of sulfur-containing free-cuttingsteel,which helps improve production efficiency and product qual-ity.It is of great significance for promoting the application and development of sulfur-containing free-cutting steel in the fields of machinery,transportation,and other industries.Future research will focus on how to control the quan-tity and morphology of inclusions in sulfur-containing steel,the impact of inclusions on the quality of steel plates after rolling,and how to reduce the amount of calcium added.

sulfur-containing free-cutting steelnozzle clogginginclusioncalcium treatmentsulfur wirecastability

周禹、巨银军、张天舒、王嵘坤、李万明

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辽宁科技大学材料与冶金学院,辽宁 鞍山 114051

湖南湘潭钢铁集团有限公司五米宽厚板厂,湖南 湘潭 411101

含硫易切削钢 水口堵塞 夹杂物 钙处理 硫线 可浇性

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(12)