首页|含铌非调质钢铸坯角部内裂纹机制分析

含铌非调质钢铸坯角部内裂纹机制分析

Analysis of corner cracks causes in cast bloom in medium carbon micro-alloyed steel containing niobium

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含铌非调质钢是裂纹敏感性钢种,在连铸过程中易产生裂纹,从而严重恶化铸坯的表面质量.针对国内某厂生产的 46MnVNbS5含铌非调质钢,采用光学显微镜、扫描电子显微镜及能谱仪、电子探针、三维刻蚀仪、高温激光共聚焦显微镜以及Thermo-Calc软件等设备手段,对含铌非调质钢铸坯角部内裂纹原因进行解析.对320 mm×425 mm规格的铸坯表面裂纹分布进行观察,发现在距内弧0~20 mm范围内无明显裂纹,仅在距内弧20 mm的试样上观察到点状坑缺陷.在距内弧 20~40 mm范围有明显裂纹,裂纹尺寸普遍大于 10 mm;距内弧表面 25 mm处,仅在铸坯低倍面观察到裂纹;在距内弧表面30、35、40 mm处,试样多个观察面均有裂纹,裂纹沿枝晶生长方向生长.利用扫描电镜分析及能谱分析确定了裂纹内部及附近存在大量硫化锰与碳氮化物的耦合析出物.对裂纹试样的表面进行腐蚀后观察发现,裂纹沿仿晶界铁素体扩展.热力学计算结果表明,在两相区夹杂物主要为硫化锰,随后会依次析出富铌碳氮化物、富钒碳氮化物,这也与试验得到的夹杂物类型相符.最后,采用高温激光共聚焦显微镜和数值模拟确定了含铌非调质钢的裂纹区(620.1~794.3℃),模拟了连铸坯角部温度场,并优化了冷却制度以避开含铌非调质钢的裂纹敏感区.为解决铸坯裂纹提供了方法和手段,具有一定现实意义.
The medium carbon micro-alloyed steel containing niobium is crack-sensitive steel,which is easy to crack in the continuous casting process and seriously deteriorates the surface quality of the bloom.The causes of corner cracks in 46MnVNbS5 steel were analyzed using an optical microscope,scanning electron microscope with energy dispersive spectrometer,three-dimensional etching technology,high temperature confocal laser scanning microscope and Thermo-Calc software.The surface crack distribution of 320 mm×425 mm casting bloom was observed,and no obvious cracks were found in the range of 0-20 mm of the inner arc,and only pitted defects were observed on the samples 20 mm away from the inner arc.There are obvious cracks in the range of 20-40 mm,and the crack size is generally greater than 10 mm.At the distance of 25 mm from the inner arc surface,cracks were observed only at the low multiplier surface.At 30 mm,35 mm,and 40 mm from the inner arc surface,there were cracks on multiple observation surfaces of the sample.The crack grows along the dendrite growth direction.A large number of cou-pling precipitates of manganese sulfide and carbonitride in and near cracks were determined by SEM-EDS.The sur-face of the crack specimen was corroded and it was found that the crack spread along the ferrite film.The thermody-namic results show that manganese sulfide is the main inclusion in the solid-liquid zone of steel.The niobium-rich carbonitride and vanadium-rich carbonitride will be precipitated successively,which is consistent with the types of inclusions obtained by experiments.The cracking zone(620.1-794.3℃)of steel containing niobium was deter-mined by high-temperature confocal laser microscopy,and numerical simulation was applied to simulate the corner temperature field of continuous casting bloom,and the cooling system was optimized to avoid the cracking zone of medium carbon micro-alloyed steel containing niobium.This study provides the methods to solve the crack of cast-ing bloom and has important practical significance.

niobiummedium carbon micro-alloyed steelcontinuous castingcrackinclusions

黎玉唐、徐瑞军、王梓菲、曾凡政、张璐、付建勋

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上海大学材料科学与工程学院先进凝固技术中心,上海 200444

上海大学省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444

湖南华菱湘潭钢铁有限公司,湖南 湘潭 411101

非调质钢 连铸 裂纹 夹杂物

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(12)