首页|固溶对2.1GPa级超高强度不锈钢组织和性能的影响

固溶对2.1GPa级超高强度不锈钢组织和性能的影响

Effect of solid solution on microstructure and property of 2.1 GPa grade ultra-high strength stainless steel

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超高强度不锈钢因具有良好的综合性能被广泛应用于航空、航天等领域.以一种新型2.1 GPa级超高强度不锈钢为研究对象,研究了不同固溶温度、时效处理对钢力学性能的影响规律,并采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、透射电子显微镜(TEM)等手段对钢的固溶和时效态的显微组织进行表征,建立了热处理-力学性能-微观组织之间的内在关联.结果表明,钢的固溶态组织为板条马氏体+残余奥氏体,原奥氏体晶粒尺寸随着固溶温度升高而增加,强度随着固溶温度升高呈降低趋势,而冲击吸收功先升高后降低;经1 050℃固溶的强度最高,但因未溶解的M6C相破坏了基体组织的连续性导致了冲击吸收功降低,1 100℃固溶的强度和冲击吸收功均低于1 080℃固溶情况,虽然前者奥氏体含量高有利于提高韧性,但粗大的晶粒导致了冲击吸收功降低.经时效后,钢的强度显著提高,1 050℃固溶+时效的强度最低;1 080℃固溶+时效的强度最高,此时抗拉强度为2 161 MPa,屈服强度1 784 MPa,塑韧性优于1 050℃和1 100℃的情况,1 080℃冲击吸收功为37.5 J,强韧性匹配最佳,在板条马氏体上析出大量细小、弥散的Laves相和M2C相,这是获得超高强度的主要原因,马氏体板条界上的薄膜状奥氏体是保持良好韧性的关键.研究钢种是目前国际上强度水平最高的不锈钢,研究成果可为提升其工程化技术成熟度提供一定的数据支撑.
Ultra-high strength stainless steel is widely used in aviation,aerospace and other fields because of its good comprehensive performance.A new type of 2.1 GPa grade ultra-high strength stainless steel was taken as the research object,and the influence law of different solid solution temperature and aging treatment on the mechanical properties of steel was investigated.Scanning electron microscope(SEM),X-ray diffractometer(XRD),transmis-sion electron microscope(TEM)and other means were used to characterize the microstructures of the steel in solid solution and aging state,and an intrinsic correlation was established between the heat treatment-mechanical properties-microstructure.The results show that the solid solution organization of the steel is slat martensite+residual austenite,the size of the original austenite grain increases with the increase of solid solution temperature,the strength shows a decreasing trend with increasing of solid solution temperature,while the impact absorption work increases firstly and then decreases.The strength of the solid solution by 1 050℃ is the highest,but due to the un-dissolved M6C phase disrupts the continuity of matrix organization resulting in low impact absorption work,the strength and the impact absorption work of solid solution by 1 100℃ are lower than the 1 080℃ solid solution.Although the former high austenite content is conducive to improving toughness,coarse grains lead to a reduction in the impact absorption work.After aging,the strength of the steel significantly improved,1 050℃ solid solution+aging has the lowest strength,while 1 080℃ solid solution+aging has the highest strength,the tensile strength is 2 161 MPa and yield strength is 1 784 MPa.Plastic toughness also better than 1 050℃ and 1 100℃,1 080℃ impact absorption work is 37.5 J,which has the best toughness match,and there are a large number of small,dif-fuse Laves phase and M2C phase precipitated in the slat martensite,which is the main reason for obtaining ultra-high strength.In the martensite slat boundary,the thin film austenite is the key to maintain good toughness.The research steel grade is the highest strength level of stainless steel in the international arena currently,and the research results can provide data support to enhance the maturity of its engineering technology.

ultra-high strengthsolution temperaturestainless steelimpact absorbing energymicrostructure

杜昌友、刘振宝、田帅、王晓辉、邱雨、赵文宇、朱心昆

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昆明理工大学材料科学与工程学院,云南 昆明 650000

钢铁研究总院有限公司特殊钢研究院,北京 100081

超高强度 固溶温度 不锈钢 冲击吸收功 显微组织

2024

钢铁
中国金属学会钢铁研究总院

钢铁

CSTPCD北大核心
影响因子:1.204
ISSN:0449-749X
年,卷(期):2024.59(12)