首页|Effect of Ta content on high temperature oxidation and hot corrosion resistance of DZ411 superalloy

Effect of Ta content on high temperature oxidation and hot corrosion resistance of DZ411 superalloy

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In order to elucidate the mechanism of the effect of Ta content on the high temperature behaviour of the alloys,the high temperature oxidation and thermal corrosion experiments were carried out on the three alloys with different Ta contents(2.72,3.10 and 4.00 wt.%).The results of high temperature oxidation and hot corrosion show that because Ta has a higher valence state than Al,it can reduce the indiffusion of O,and the rate at which Ta diffuses within the alloy matrix is relatively slow since it has a larger atomic radius.As a result,the diffusion of the Al element is inhibited as the Ta content increases.Therefore,adding Ta inhibits the formation of Al2O3 in the surface oxide and promotes the formation of Cr2O3.Thus,Ta promotes oxidised film growth on the sample surface,which inhibits the diffusion of S,O and other elements into the matrix.Additionally,Cr2O3 is not easy to dissolve in molten salt,which ultimately makes the alloy have high oxidation resistance and thermal corrosion resistance.

Ni-based superalloyTantalumMicrostructureHot corrosionThermal oxidationDirectional solidification

Peng Peng、Yi-fan Ma、Zi-jie Liu、Su-jun Lu、Yuan-li Xu、Xu-dong Zhang、Zhi-kun Ma

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School of Materials and Energy,Lanzhou University,Lanzhou 730000,Gansu,China

State Key Laboratory of Nickel and Cobalt Resources Comprehensive Utilization,Jinchang 737100,Gansu,China

2024

钢铁研究学报(英文版)
钢铁研究总院

钢铁研究学报(英文版)

CSTPCD
影响因子:0.584
ISSN:1006-706X
年,卷(期):2024.31(12)