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高镁含硼磁铁精矿球团矿固结机制及还原特性

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高镁含硼磁铁精矿球团矿的应用有助于实现高镁含硼磁铁精矿中硼和铁的高效分离.然而,目前高镁含硼磁铁精矿配比对球团矿固结行为的影响研究较少,对球团矿还原性所产生的影响不明确.研究了高镁含硼磁铁精矿配比对球团矿强度和还原性的影响规律和作用机制,并根据球团矿固结机制研究了通过降低焙烧温度来提高球团矿还原度的方法.研究结果表明:普通磁铁精矿中高镁含硼磁铁精矿配比的增加有助于提高球团矿内部尖晶石型镁铁氧体相含量,有益于改善赤铁矿晶粒形态,促进"赤铁矿-尖晶石型镁铁氧体"结构生成,从而可以提高球团矿强度.然而,在配加高镁含硼磁铁精矿制备球团矿时,球团矿焙烧过程中生成的尖晶石型镁铁氧体会对球团矿的还原性产生较大的负面影响.因此,在保证球团矿强度和一定还原性的情况下,配加高镁含硼磁铁精矿的球团矿焙烧温度不宜超过1150 ℃.
Consolidation mechanism and reduction characteristics of high-magnesium boron-bearing magnetite concentrate pellets
The incorporation of high-magnesium boron-bearing magnetite concentrate in pellet production facilitates the efficient separation of boron and iron within the concentrate.However,the limited research has been conducted on the influence of the ratio of high-magnesium boron-bearing magnetite concentrate on the pellet consolidation mechanism and reduction characteristics.The effects and mechanisms of varying the ratio of high-magnesium boron-bearing magnetite concentrate on the strength and reducibility of the pellets were investigated.Additionally,it explores the potential for enhancing reduction characteristics by lowering the firing temperature during pellet preparation based on the consolidation mechanism of the pellets.The results indicate that the increase in the proportion of high magnesium boron magnetite concentrate in ordinary magnetite concentrates helps to increase the content of spinel type magnesium ferrite phase inside the pellets,improve the grain morphology of hematite,promote the formation of"hematite spinel type magnesium ferrite"structure,and thus improve the strength of the pellets.However,during the preparation of pellets with the addition of high-magnesium boron-bearing magnetite concentrate,the spinel-type magnesium ferrite generated during the firing process can have a significant negative impact on the reducibility of the pellets.Therefore,to ensure both the strength of the pellets and a certain level of reducibility,the firing temperature of pellets containing high-magnesium boron-bearing magnetite concentrate should not exceed 1 150 ℃.

high-magnesium boron-bearing magnetite concentratepelletconsolidation mechanismcold crushing strengthreduction characteristicsreducibility index

温宝良、胡正洪、董申奥、张旭、李国兴、李家新、杨佳龙

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安徽工业大学冶金工程学院,安徽马鞍山 243032

抚顺新钢铁有限责任公司技术中心,辽宁 抚顺 113001

高镁含硼磁铁精矿 球团矿 固结机制 抗压强度 还原特性 还原度

2024

钢铁研究学报
中国钢研科技集团有限公司

钢铁研究学报

CSTPCD北大核心
影响因子:0.997
ISSN:1001-0963
年,卷(期):2024.36(11)