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转炉熔池冶金规律特征解析和反应三区模型探讨

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转炉冶炼机制模型飞速发展但仍存在不少问题,如模型参数与实际吹炼和加料工况脱节、预测结果与实际情况不符等.以转炉熔池多反应区域、最小吉布斯自由能理论、热力学和动力学耦合反应等分析方法为基础建立冶金模型已逐渐成为业界共识.分析了转炉熔池反应过程钢液和炉渣成分变化,论证了冶炼过程冶金规律共性问题.通过解析熔池反应重要特征,提出了冶炼过程FeO积累和消耗同步变化机制、反应界面层平衡状态和冶炼过程渣料成渣路线.基于转炉多反应区域理论划分熔池为"气体-钢液"射流冲击区、"炉渣-金属液滴-炉气"乳化区和"炉渣-钢液(金属液滴)"炉渣区.建立了3个反应区域动态调控的氧分配模型,其取值范围为10%~20%:45%~65%:40%~25%.基于熔池混匀搅拌转炉反应三区模型的应用研究表明,当量综合搅拌能在0.60~0.75范围时,反应界面当量传质系数变化区间为1.019~1.024.
Analyzing metallurgical characteristics of converter melt pool and exploring mode of three reaction zones
The mechanism model of converter smelting has developed rapidly,but there are still many problems,such as the disconnection between model parameters and actual blowing and feeding conditions,and the inconsistency between predicted results and actual situations.The establishment of metallurgical models based on mechanism analysis methods such as multiple reaction zones in the converter melt,minimum Gibbs free energy theory,thermodynamic and kinetic coupling reactions has gradually become a consensus in the industry.Changes in the composition of molten steel and slag during the converter melt reaction process were studied and demonstrated the common issues of metallurgical laws in the smelting process.The analysis of the important characteristics of the molten pool reaction was also conducted.Moreover,the mechanism of synchronous changes in FeO accumulation and consumption during the smelting process,the equilibrium state of the reaction interface layer,and the slag-forming route of slag material in the smelting process were proposed.Based on the theory of multiple reaction zones in the converter,the molten pool was divided into"gas-steel liquid"jet impact zone,"slag-metal droplets-furnace gas"emulsification zone,and"slag-steel liquid(metal droplets)"slag zone.An oxygen allocation model for dynamic regulation of three reaction regions with values ranging from 10%~20%:45%~65%:40%~25%was established.Application of the model based on the mixing and stirring of the melt pool in the three reaction zones of the converter showed that when the comprehensive stirring energy was in the range of 0.60~0.75,the variation range of the equivalent mass transfer coefficient at the reaction interface was 1.019~1.024.

converterthree reaction zonesminimum Gibbs free energythermodynamic and kinetic couplingmetallurgical model

蔡伟、吴巍、杨利彬

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钢铁研究总院有限公司冶金工艺研究所,北京 100081

转炉 反应三区 最小吉布斯自由能 热力学与动力学耦合反应 冶金模型

2024

钢铁研究学报
中国钢研科技集团有限公司

钢铁研究学报

CSTPCD北大核心
影响因子:0.997
ISSN:1001-0963
年,卷(期):2024.36(12)
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