首页|CA6细粉加入量对钢包永久衬用Al2O3-CaO系隔热浇注料抗渣性能的影响

CA6细粉加入量对钢包永久衬用Al2O3-CaO系隔热浇注料抗渣性能的影响

Effect of CA6 grain addition on the slag resistance of Al2O3-CaO insulating castable for permanent lining of ladles

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为提高钢包周转过程中的保温性能,钢水冶炼过程常使用保温隔热材料以适应连铸钢水温度的变化,满足炉外精炼和连铸工艺需求.本文选用六铝酸钙(CA6)、97 电熔镁砂、氧化铝微粉、白刚玉等为原料,纯铝酸盐水泥为主要结合剂,加入PC60 减水剂和有机纤维,制备出用于钢包永久衬的隔热浇注料.探究了CA6 细粉加入量对隔热浇注料抗渣性能的影响.试验结果表明:1 100℃煅烧后主要有颗粒状的CA2 生成,同时在基质内有大量片状的CA6;当煅烧温度升至 1 500℃,试样中的CA2 完全转化成了CA6,在试样内部仅检测出Al2O3 和CA6 的特征峰;随着CA6加入量的增加,试样的常温抗折强度和耐压强度呈现先上升后下降的趋势;同时,试样的导热系数呈现下降的趋势;当添加质量分数为 10%CA6 时,试样的抗渣侵蚀性能较佳.
To improve the insulation performance of ladles during turnover,insulating materials are often used in the liquid steel smelting process to fit the temperature changes of liquid steel in continuous casting and meet the requirements of secondary refining and continuous casting processes.The dedicated insulating castable for permanent lining of ladles was prepared with raw materials including calcium hexaluminate,fused magnesia 97%,alumina micro powder,white fused alumina,etc.In its preparation,pure aluminate cement served as the main binderand PC60 water-reducing agent and organic fibers were added.Then the effect of CA6 grain addition on the slag resistance of insulating castable was studied.According to the experiment,when the calcination temperature was 1 100℃,the main generated product was granular CA2,and a large number of sheet-like CA6 will be generated inside the matrix.When the calcination temperature rose to 1 500℃,CA2 in the sample was completely transformed into CA6,and only the characteristic peaks of Al2O3 and CA6 were detectable inside the sample.As the adding amount of CA6 increased,the flexural strength and compressive strength of the sample under room temperature first increased and then decreased.Besides,the thermal conductivity of the sample gradually decreased.The best slag erosion resistance performance was observed when 10%CA6(w)was added.

Al2O3-CaO insulating castableCA6Mechanical propertiesSlag resistance performance

王国林、殷超凡、白宏宇、白帆、王黎、董宾宾

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偃师中岳耐火材料有限公司,471924 洛阳

洛阳理工学院 材料科学与工程学院,471023 洛阳

Al2O3-CaO系隔热浇注料 CA6 力学性能 抗渣性能

河南省重点研发专项洛阳市重大科技创新专项

2311112303002301009A

2024

耐火与石灰
中冶焦耐工程技术有限公司

耐火与石灰

影响因子:0.057
ISSN:1673-7792
年,卷(期):2024.49(3)