光学精密工程2024,Vol.32Issue(3) :317-323.DOI:10.37188/OPE.20243203.0317

光强非线性响应下的光致热弹光谱光强修正

Light intensity correction for light-induced thermoelastic spectroscopy based on nonlinear response of light intensity

陈祥 刘浩 姚路 许振宇 胡迈 阚瑞峰
光学精密工程2024,Vol.32Issue(3) :317-323.DOI:10.37188/OPE.20243203.0317

光强非线性响应下的光致热弹光谱光强修正

Light intensity correction for light-induced thermoelastic spectroscopy based on nonlinear response of light intensity

陈祥 1刘浩 2姚路 1许振宇 1胡迈 3阚瑞峰1
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作者信息

  • 1. 中国科学院 合肥物质科学研究院,安徽 合肥 230031
  • 2. 中国科学院 合肥物质科学研究院,安徽 合肥 230031;中国科学技术大学,安徽 合肥 230026
  • 3. 香港中文大学,香港 999077
  • 折叠

摘要

提出了基于光强非线性响应的光致热弹光谱光强修正方法,实现了激光光强的准确修正.控制DFB激光器工作于波长调制模式,设置激光调制频率为16 369.75 Hz,通过光纤放大器增强其出射光强非线性项的幅值,光束经多次反射池后汇聚于石英音叉根部激发光热信号,采用数字锁相放大器解调得到对应的谐波信号,通过多项式拟合谐波信号背景,反演得到与浓度及光强分别对应的谐波信号.实验结果表明,当光强从22.03 mW变化至3.16 mW,谐波信号背景幅值与光强具有良好的线性关系,线性相关系数大于0.998,归一化后的谐波信号幅值波动小于0.37%.针对甲烷测量,系统在较大的浓度范围内具有良好的线性响应,谐波信号信噪比表明系统的最低检测限达0.22×10-6.该研究为光致热弹光谱的光强修正提供了一种新的方法,可有效提高LITES系统在长期测量应用中的稳定性.

Abstract

This study presents a method for correcting light intensity in light-induced thermoelastic spec-troscopy(LITES)using a nonlinear light intensity response,enabling precise light intensity corrections.The DFB laser,set to a wavelength modulation mode at a frequency of 16369.75 Hz,benefits from en-hanced nonlinear light intensity due to a fiber amplifier.The laser beam traverses a multi-pass cell before fo-cusing on the quartz tuning fork(QTF)base,generating a thermoelastic signal.A lock-in amplifier demod-ulates the harmonic signal,and polynomial fitting of the harmonic signal's baseline extracts harmonics relat-ed to both concentration and light intensity.Experimental data reveal a strong linear correlation(coeffi-cient>0.998)between the baseline amplitude of the harmonic signal and light intensity as it varies from 22.03 mW to 3.16 mW,with normalized harmonic signal amplitude variation under 0.37%.In methane detection,the system demonstrates a robust linear response across a broad concentration range,with harmonic signal noise ratios indicating a detection threshold as low as 0.22×10-6.This research offers a novel approach for LITES light intensity correction,significantly enhancing system stability for pro-longed measurements.

关键词

光致热弹光谱/谐波信号/非线性响应/多项式拟合/光强修正

Key words

light-induced thermoelastic spectroscopy/harmonic signal/nonlinear response/polynomial fitting/light intensity correction

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基金项目

国家重点研发计划资助项目(2020YFA0405703)

装备发展部型号研制项目(2005CS016)

出版年

2024
光学精密工程
中国科学院长春光学精密机械与物理研究所 中国仪器仪表学会

光学精密工程

CSTPCD北大核心
影响因子:2.059
ISSN:1004-924X
参考文献量3
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