光学精密工程2024,Vol.32Issue(5) :653-660.DOI:10.37188/OPE.20243205.0653

Ag/Bi2O3纳米块自供能紫外探测器的制备及性能

Preparation and performance of self-powered Ag/Bi2O3 nanoblocks ultraviolet photodetector

方向明 周起成 孙宇 乔志铭 耿秋丹 高世勇
光学精密工程2024,Vol.32Issue(5) :653-660.DOI:10.37188/OPE.20243205.0653

Ag/Bi2O3纳米块自供能紫外探测器的制备及性能

Preparation and performance of self-powered Ag/Bi2O3 nanoblocks ultraviolet photodetector

方向明 1周起成 2孙宇 2乔志铭 2耿秋丹 2高世勇2
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作者信息

  • 1. 太原学院 材料与化学工程系,山西 太原 030032
  • 2. 哈尔滨工业大学 材料科学与工程学院,黑龙江 哈尔滨 150001
  • 折叠

摘要

为了实现在无外部供能下对紫外光的有效探测,基于Ag修饰的Bi2O3纳米块(Ag/Bi2O3)纳米块制备了自供能紫外探测器.通过煅烧法制备Bi2O3 纳米块,随后采用室温溶液法在其表面沉积Ag纳米粒子,进而成功制备了Ag/Bi2O3 纳米块,且对所制备样品的晶体结构和微观形貌等进行了表征.结果表明,Ag/Bi2O3 纳米块的平均尺寸约为1 μm,且Ag纳米粒子随机分布在Bi2O3纳米块表面.将涂覆Ag/Bi2O3纳米块的FTO作为工作电极,并进一步构建了自供能紫外探测器.在365 nm的紫外光照射下,Ag/Bi2O3纳米块紫外探测器能在零偏压下实现对紫外光的快速检测,这证实其具有自供能特性.相比于Bi2O3纳米块紫外探测器,Ag/Bi2O3纳米块紫外探测器的光电流得到明显提升,上升和下降时间分别缩短至29.1 ms和40.2 ms,并具有良好的循环稳定性.

Abstract

To effectively detect ultraviolet(UV)light without an external power source,a self-powered UV photodetector(UVPD)was developed using Ag/Bi2O3 nanoblocks.Initially,Bi2O3 nanoblocks were prepared through a calcination process,followed by the successful synthesis of Ag/Bi2O3 nanoblocks by de-positing Ag nanoparticles on their surface via a solution reaction method at room temperature.The crystal structure and microstructures of the samples were analyzed,revealing that the Ag/Bi2O3 nanoblocks had an average diameter of approximately 1 μm,with Ag nanoparticles randomly distributed on the surface of the Bi2O3 nanoblocks.The Ag/Bi2O3 nanoblocks were then coated on FTO as the working electrode,lead-ing to the construction of the self-powered UVPD.Upon exposure to UV light(365 nm),the Ag/Bi2O3 nanoblocks UVPD quickly detected UV light at zero bias voltage,showcasing its self-powered capability.Compared to the Bi2O3 nanoblocks UVPD,the Ag/Bi2O3 nanoblocks UVPD displayed significantly im-proved photocurrents,with rise and decay times reduced to 29.1 ms and 40.2 ms,respectively,and dem-onstrated excellent cycling stability.

关键词

紫外探测器/Bi2O3纳米块/Ag纳米粒子/自供能探测

Key words

ultraviolet photodetector/Bi2O3 nanoblocks/Ag nanoparticles/self-powered detection

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基金项目

国家重点研发计划(2019YFA0705201)

山西省高等学校科技创新项目(2022L590)

中央高校基本科研业务费专项(HIT.DZJJ.2023002)

太原学院一般科研项目(23TYYB09)

出版年

2024
光学精密工程
中国科学院长春光学精密机械与物理研究所 中国仪器仪表学会

光学精密工程

CSTPCD北大核心
影响因子:2.059
ISSN:1004-924X
参考文献量25
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