首页|Ag/Bi2O3纳米块自供能紫外探测器的制备及性能

Ag/Bi2O3纳米块自供能紫外探测器的制备及性能

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为了实现在无外部供能下对紫外光的有效探测,基于Ag修饰的Bi2O3纳米块(Ag/Bi2O3)纳米块制备了自供能紫外探测器.通过煅烧法制备Bi2O3 纳米块,随后采用室温溶液法在其表面沉积Ag纳米粒子,进而成功制备了Ag/Bi2O3 纳米块,且对所制备样品的晶体结构和微观形貌等进行了表征.结果表明,Ag/Bi2O3 纳米块的平均尺寸约为1 μm,且Ag纳米粒子随机分布在Bi2O3纳米块表面.将涂覆Ag/Bi2O3纳米块的FTO作为工作电极,并进一步构建了自供能紫外探测器.在365 nm的紫外光照射下,Ag/Bi2O3纳米块紫外探测器能在零偏压下实现对紫外光的快速检测,这证实其具有自供能特性.相比于Bi2O3纳米块紫外探测器,Ag/Bi2O3纳米块紫外探测器的光电流得到明显提升,上升和下降时间分别缩短至29.1 ms和40.2 ms,并具有良好的循环稳定性.
Preparation and performance of self-powered Ag/Bi2O3 nanoblocks ultraviolet photodetector
To effectively detect ultraviolet(UV)light without an external power source,a self-powered UV photodetector(UVPD)was developed using Ag/Bi2O3 nanoblocks.Initially,Bi2O3 nanoblocks were prepared through a calcination process,followed by the successful synthesis of Ag/Bi2O3 nanoblocks by de-positing Ag nanoparticles on their surface via a solution reaction method at room temperature.The crystal structure and microstructures of the samples were analyzed,revealing that the Ag/Bi2O3 nanoblocks had an average diameter of approximately 1 μm,with Ag nanoparticles randomly distributed on the surface of the Bi2O3 nanoblocks.The Ag/Bi2O3 nanoblocks were then coated on FTO as the working electrode,lead-ing to the construction of the self-powered UVPD.Upon exposure to UV light(365 nm),the Ag/Bi2O3 nanoblocks UVPD quickly detected UV light at zero bias voltage,showcasing its self-powered capability.Compared to the Bi2O3 nanoblocks UVPD,the Ag/Bi2O3 nanoblocks UVPD displayed significantly im-proved photocurrents,with rise and decay times reduced to 29.1 ms and 40.2 ms,respectively,and dem-onstrated excellent cycling stability.

ultraviolet photodetectorBi2O3 nanoblocksAg nanoparticlesself-powered detection

方向明、周起成、孙宇、乔志铭、耿秋丹、高世勇

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太原学院 材料与化学工程系,山西 太原 030032

哈尔滨工业大学 材料科学与工程学院,黑龙江 哈尔滨 150001

紫外探测器 Bi2O3纳米块 Ag纳米粒子 自供能探测

国家重点研发计划山西省高等学校科技创新项目中央高校基本科研业务费专项太原学院一般科研项目

2019YFA07052012022L590HIT.DZJJ.202300223TYYB09

2024

光学精密工程
中国科学院长春光学精密机械与物理研究所 中国仪器仪表学会

光学精密工程

CSTPCD北大核心
影响因子:2.059
ISSN:1004-924X
年,卷(期):2024.32(5)
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