首页|基于双光子聚合效应加工大深宽比纳米柱子和超构表面的研究

基于双光子聚合效应加工大深宽比纳米柱子和超构表面的研究

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文章基于双光子聚合(TPP)效应,即双光子光刻(TPL)3D打印技术,实现了超衍射极限和高复杂结构的加工,实现了加工大深宽比的纳米柱子及由这些纳米柱子构成的超构表面.本文研究了不同TPP工艺参数对IP-Dip光刻胶微结构尺寸的影响,同时对这些参数进行了优化.文章的创新在以下两点:(1)分析了不同激光参数下纳米柱的尺寸变化,同时找出线宽最小对应的阈值参数来制备大深宽比的纳米结构.(2)对于加工步骤的优化,在显影步骤后加入了紫外灯固化和超临界二氧化碳干燥等步骤,以保证加工出的纳米结构不倒塌且具有良好的稳定性.文章使用以上改良技术,稳定的制备出具有最大深宽比接近15:1、最小线宽214.80nm的矩形纳米柱,以及最大深宽比接近20:1、最小直径145.44nm的圆形纳米柱,并且将制备出的大高宽比纳米柱应用在超构表面的加工中.
Research on the fabrication of nanopillars with high aspect ratio and metasurfaces based on two-photon polymerization
The article is based on the Two Photon Polymerization(TPP)effect,namely the Two Photon Lithography(TPL)3D printing technology,which achieves the fabrication of ultra diffraction limits and highly complex structures.It also achieves the processing of large aspect ratio nanopillars and metasurfaces composed of these nanopillars.The effects of different TPP process parameters on the nanopillars size of IP-Dip photoresist are studied,and the parameters are opti-mized.The innovation of this paper is in the following two points:(1)Analyzed the size changes of nanopillars under dif-ferent laser parameters,and identified the threshold parameter corresponding to the minimum linewidth to prepare nano-pillars with high aspect ratios.(2)For the optimization of fabrication steps,steps such as UV curing and supercritical carbon dioxide drying were added after the development step,are used to ensure that the nanopillars does not collapse and has good stability.The rectangular nanopillars with a maximum aspect ratio of nearly 15∶1 and a minimum line width of 214.80nm are prepared stably,and the circular nanopillars with a maximum aspect ratio of nearly 20∶1 and a minimum diameter of 145.44nm are prepared stably,and the prepared large aspect ratio nanopillars are applied in the fabrication of metasurfaces.

two-photon 3D printingtwo-photon polymerizationnanopillarshigh aspect ratiometasurfaces

李岳隆、谢周宇、张大伟、陶春先、徐学科、文静

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上海理工大学光电信息与计算机工程学院,上海 200093

恒迈光学机密机械(杭州)有限公司,浙江杭州 311421

双光子3D打印 双光子聚合效应 纳米柱 大深宽比 超构表面

国家重点研发计划国家自然科学基金国家自然科学基金上海理工大学专业学位研究生实践基地项目

2018YFA0701800NSFC62175153

2024

光学技术
北京兵工学会 北京理工大学 中国北方光电工业总公司

光学技术

CSTPCD北大核心
影响因子:0.441
ISSN:1002-1582
年,卷(期):2024.50(3)
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