工业催化2024,Vol.32Issue(3) :9-19.DOI:10.3969/j.issn.1008-1143.2024.03.002

丁烷脱氢工艺及催化剂研究进展

Research progress on butane dehydrogenation process and catalysts

舒洁 毛清国 白鹏 吴萍萍 阎子峰
工业催化2024,Vol.32Issue(3) :9-19.DOI:10.3969/j.issn.1008-1143.2024.03.002

丁烷脱氢工艺及催化剂研究进展

Research progress on butane dehydrogenation process and catalysts

舒洁 1毛清国 2白鹏 1吴萍萍 1阎子峰1
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作者信息

  • 1. 中国石油大学(华东)化学化工学院,山东青岛266580
  • 2. 辽宁宝来生物能源有限公司,辽宁盘锦124000
  • 折叠

摘要

C4烯烃作为石油化工和聚合物行业的基础原料被广泛用于合成橡胶、塑料和特种燃料等的生产.由低碳烷烃向C4烯烃的转化,不仅可以有效缓解我国低碳烯烃紧缺的难题,而且可以大大提升低碳烷烃的附加值.综述近年来国内外丁烷催化脱氢的技术现状与研究进展,重点论述正丁烷脱氢反应的机理、催化剂活性组分、载体及助剂对催化脱氢性能的影响,概述脱氢催化剂的失活原因,并对丁烷脱氢催化剂的研究前景进行展望.

Abstract

C4 olefin is widely applied as a basic chemical raw stock in the petrochemical and polymer industries for the synthesis of special fuels,rubber,plastics,etc. Conversion of low-carbon alkanes to C4 olefins not only effectively alleviates the shortage of low-carbon olefins in China,but also greatly increases the added value of low-carbon alkanes. This paper reviews the current status and research progress on butane catalytic dehydrogenation technology both domestically and internationally in recent years. The mechanism of n-butane dehydrogenation reaction,the effects of catalyst active components,supports,and additives on catalytic dehydrogenation performance and the reasons for deactivation of dehydrogenation catalysts are summarized. The research prospects of butane dehydrogenation process and catalysts are prospected.

关键词

石油化学工程/正丁烯/正丁烷/脱氢催化剂

Key words

petrochemical engineering/n-butene/n-butane/dehydrogenation catalyst

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基金项目

山东省自然科学基金面上项目(ZR2021ME020)

出版年

2024
工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
参考文献量67
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