工业催化2024,Vol.32Issue(4) :18-29.DOI:10.3969/j.issn.1008-1143.2024.04.003

碱性水电解镍基析氧催化材料最新进展

Recent developments on Ni-based oxygen evolution materials for alkaline water electrolysis

侯朋飞 单小勇 白建明
工业催化2024,Vol.32Issue(4) :18-29.DOI:10.3969/j.issn.1008-1143.2024.04.003

碱性水电解镍基析氧催化材料最新进展

Recent developments on Ni-based oxygen evolution materials for alkaline water electrolysis

侯朋飞 1单小勇 1白建明1
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作者信息

  • 1. 华电重工股份有限公司,北京 100070
  • 折叠

摘要

通过碱性水电解制氢技术,将可再生能源转化为绿氢,是实现能源储存和分布再平衡的最具应用前景的方法.开发低过电位的碱性水电解电催化剂是降低绿氢电耗和成本的必要条件.镍基材料是目前商业化碱性水电解制氢应用最广泛的电催化剂,但不断追求高电流密度和快速动力学的高效电催化剂是提高碱性水电解制氢设备性能的主要研究方向之一.综述碱性水电解制氢镍基析氧催化材料的研究进展,包括反应机理、评价指标和制备-结构-性能关系.同时,对目前存在的问题进行剖析,并对未来发展方向进行展望.

Abstract

Converting renewable energy to green hydrogen by alkaline hydroelectrolysis is the most promis-ing method to rebalance energy storage and distribution.The development of alkaline hydroelectrolysis cat-alysts with low overpotential is a necessary to reduce the power consumption and cost of green hydrogen.Nickel-based materials are the most widely used commercial electrocatalysts for hydrogen pro-duction by alkaline electrolysis,and the pursuit of high current density and fast kinetics of efficient elec-trocatalysts is one of the main research directions to improve the performance of alkaline hydrolysis equip-ment.In this paper,the research progress on electrolysis of nickel-based electrocatalysts by alkaline hydro-power is reviewed,including reaction mechanism,evaluation index and preparation-structure-performance relationship.At the same time,the existing problems are analyzed,and the future development direction is prospected.

关键词

催化剂工程/碱性水电解//反应机理/析氧反应/镍基催化剂

Key words

catalyst engineering/alkaline water electrolysis/hydrogen/reaction mechanism/oxygen evolu-tion reaction/Ni-based electrocatalysts

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出版年

2024
工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
参考文献量42
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