首页|过氧化氢生产中新型Pd/Al2O3催化剂工业中试应用

过氧化氢生产中新型Pd/Al2O3催化剂工业中试应用

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自制一种粒径为3.5 mm×3.0 mm的齿球形Al2O3载体,采用浸渍法负载活性组分Pd制备固定床蒽醌加氢制过氧化氢Pd/Al2O3催化剂.该催化剂具有颗粒粒径与孔径大、适宜的Pd活性组分浸渍层等优点.,小试和中试评价结果表明,制备的Pd/Al2O3催化剂表现出较高的加氢活性、选择性和稳定性,且氢化塔的床层压力降小,具有良好的工业应用前景.
Industrial application of new Pd/Al2O3 catalyst for production of hydrogen peroxide
A new Pd/Al2O3 catalyst for fixed-bed anthraquinone hydrogenation was prepared by impregna-tion on a self-made 3.5 mm×3.0 mm spherical Al2O3 support.The Pd/Al2O3 catalyst exhibited a larger particle size,larger pore diameter,and thinner layer of the active component.The performance of catalyst in anthraquinone hydrogenation was studied in laboratory and pilot test evaluation devices.The results showed that the catalyst exhibited high activity,selectivity and stability.Moreover,the pressure drop was small for the reaction unit.It indicated that the Pd/Al2O3 catalyst had a good prospects if industrial appli-cation.

catalyst engineeringhydrogen peroxideanthraquinone hydrogenationPd/Al2O3 catalystindustrial application

王剑辉、李明杰、董继龙、安霓虹、魏建伟

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贵研铂业股份有限公司,稀贵金属综合利用新技术国家重点实验室,云南昆明 650000

贵研工业催化剂(云南)有限公司,云南昆明 650106

催化剂工程 过氧化氢 蒽醌加氢 Pd/Al2O3催化剂 中试评价

云南贵金属实验室专项

YPML-2023050216

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(4)
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