首页|氢燃料电池用催化剂的制备和性能研究

氢燃料电池用催化剂的制备和性能研究

扫码查看
氢燃料电池是一种能够将化学能直接转化为电能的能量转化装置,具有转化效率高、清洁环保等优点,被认为是21世纪最有前途的新能源技术.催化剂作为氢燃料电池的关键材料,直接影响电池的使用寿命.通过以炭黑为基体、血晶素为前驱体,通过自组装热解两步法制备复合载体,并负载铂制备Pt/Fe-N-C/EC复合催化剂.考察催化剂的电化学性能,并将其制备成膜电极组装单电池测试电池性能.结果表明,制备的铂炭催化剂具有良好的电化学性能,质量比活性可达183.26 mA·mg-1,电化学活性面积可达92.79 m2·g-1,膜电极组装的单池在DOE加速耐久30 000圈实验后,其在0.8 A·cm-2处电压值衰减18 mV,电化学活性面积衰减37.64%,符合DOE标准.
Preparation and performance study of catalyst for hydrogen fuel cells
Hydrogen fuel cells is an energy conversion device which can directly convert chemical energy to electrical energy.Hydrogen fuel cells has advantages of high conversion efficiency,clean and environ-mental protection,and is considered to be the most promising new energy technology in the 21st century.As the key material of hydrogen fuel cells,catalysts directly affect the service life of batteries.In this paper,the Pt/Fe-N-C/EC composite catalyst was prepared by using carbon black as matrix and haplogenin as precursor through self-assembly pyrolysis.The electrochemical performance of the catalyst was investigated,and the membrane electrode was prepared to assemble a single battery to test the battery per-formance.The experimental results show that the prepared platinum-carbon catalyst has good electrochem-ical performance,the mass specific activity can reach 183.26 mA·mg-1,the electrochemical active area can reach 92.79 m2·g-1,and the single cell assembled by the membrane electrode has a voltage value attenuation of 18 mv at 0.8 A·cm-2 and an ECSA attenuation of 37.64%after the DOE accelerated endurance 30 000 revolutions.The prepared catalyst meets the DOE standard.

energy chemistryhydrogen fuel cellsPt/C catalystFe-N-Cmembrance electrode perform-ance

颜攀敦、邱晨曦、陈丹、张洁兰

展开 >

西安凯立新材料股份有限公司,陕西西安 710201

新型贵金属催化剂研发技术国家地方联合工程研究中心,陕西西安 710201

陕西省催化材料与技术重点实验室,陕西西安 710201

西安市催化材料与技术重点实验室,陕西西安 710201

展开 >

能源化学 氢燃料电池 铂炭催化剂 Fe-N-C 膜电极性能

陕西省重点产业创新链项目(2021)西安市重大技术攻关集群项目(2022)陕西省重点研发计划"两链"融合项目(2023)

2021ZDLGY13-0421ZDJSGG-QCY2-00052023-LL-QY-36

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(4)
  • 5