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宽温稀土基SCR脱硝催化剂研究进展

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氮氧化物(NOx)是雾霾、酸雨和臭氧的重要前体物,燃煤电厂等固定源和柴油车等移动源的烟气脱硝迫在眉睫.氨气选择性催化还原技术(NH3-SCR)是目前最有效的烟/尾气脱硝技术.为满足NOx排放标准,NH3-SCR催化剂需在较宽温度范围内具有高效的脱硝活性和稳定性.稀土材料因独特的电子结构,可调节的表面酸性和氧化还原性,在脱硝领域应用前景广泛.综述中低温及中高温稀土基金属氧化物SCR脱硝催化剂最新研究进展,分子筛SCR脱硝催化剂制备方法,包括离子交换法、一锅法及绿色合成法,并总结了目前宽温SCR催化剂的研究热点及挑战.
Research progress on rare earth-based catalysts for SCR with wide temperature window
Nitrogen oxides(NOx)are important precursors of haze,acid rain and ozone,and flue gas deni-trification of stationary sources such as coal-fired power plants and mobile sources such as diesel vehicles is imminent.Ammonia selective catalytic reduction(NH3-SCR)is currently the most effective flue gas/exhaust denitrification technology.In order to meet NOx emission standards,NH3-SCR catalysts need to have efficient denitrification activity and stability over a wide temperature range.Rare earth materials have a wide range of applications in denitrification due to their unique electronic structure,adjustable surface acidity and redox properties.The latest research progress of medium-low and medium-high temperature rare earth-based metal oxide SCR denitrification catalysts,the preparation methods of molecular sieve SCR denitrification catalysts,including ion exchange method,one-pot method and green synthesis method,are reviewed,and the current research hotspots and challenges of wide-temperature SCR catalysts are summarized.

catalyst engineeringwide temperature windowrare earth-based catalysts for SCRmetal oxidesmolecular sieves

于威威、刘优林、沈岳松

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南京工业大学材料科学与工程学院,江苏南京 211816

催化剂工程 宽温度窗口 稀土基脱硝催化剂 金属氧化物 分子筛

国家重点研发计划

2022YFB3504102

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(5)
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