工业催化2024,Vol.32Issue(6) :50-56.DOI:10.3969/j.issn.1008-1143.2024.06.008

La2O3修饰V2O5-WO3/TiO2催化剂的低温脱硝性能

Low-temperature NH3-SCR performance of La2O3-modified V2O5-WO3/TiO2 catalyst

孔杨 张泽凯 李浙飞 赵博 卢晗锋
工业催化2024,Vol.32Issue(6) :50-56.DOI:10.3969/j.issn.1008-1143.2024.06.008

La2O3修饰V2O5-WO3/TiO2催化剂的低温脱硝性能

Low-temperature NH3-SCR performance of La2O3-modified V2O5-WO3/TiO2 catalyst

孔杨 1张泽凯 1李浙飞 2赵博 2卢晗锋1
扫码查看

作者信息

  • 1. 浙江工业大学化学工程学院工业催化学科催化反应工程研究所,浙江杭州 310014
  • 2. 浙江德创环保科技股份有限公司,浙江绍兴 312000
  • 折叠

摘要

采用稀土金属氧化物La2O3来修饰V2O5-WO3/TiO2催化剂,改善其低温催化性能.通过改变La2O3含量及焙烧温度,并借助XRD、BET、SEM、TEM、NH3-TPD、H2-TPR及XPS等表征手段,讨论了 La2O3-V2O5-WO3/TiO2催化剂结构与NH3-SCR低温性能之间的内在关联.结果发现,La2V6W5/TiO2催化剂活性最佳,以NO转化率90%为标准,其工作窗口温度范围下限低至160℃.La2O3的加入提升了催化剂中V4+浓度,改善了氧化还原能力,同时使表面的氧空位吸附氧物种得到增加,进而提升了 La2O3-V2O5-WO3/TiO2催化剂的低温脱硝性能.

Abstract

The rare earth metal oxide La2O3 was introduced to modify the V2O5-WO3/TiO2 catalyst to improve its low-temperature catalytic performance.By adjusting the La2O3 content and calcined tempera-ture,and using a series of characterization methods such as XRD,BET,SEM,TEM,NH3-TPD,H2-TPR and XPS,the intrinsic correlation between the structure of La2O3-V2O5-WO3/TiO2 catalyst and its NH3-SCR performance in the low temperature range was discussed.The results showed that the La2V6W5/TiO2 catalyst had the best activity.Using 90%NO conversion as the criteria,the lower limit of the temperature window extended to 160 ℃.Its activity improvement was attributed to the addition of La2O3,which increased the concentration of V4+in the catalyst to improve the redox capacity and increase the oxygen vacancies on the surface,thereby improving the low-temperature performance of the catalyst.

关键词

催化剂工程/脱硝/低温/钒基催化剂/La2O3/氧空位

Key words

catalyst engineering/denitrification/low-temperature/vanadium-based catalysts/La2O3/oxygen vacancy

引用本文复制引用

基金项目

绍兴市科技计划产业关键技术攻关计划(2022B41007)

出版年

2024
工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
参考文献量15
段落导航相关论文