首页|Cu2O/Ag/g-C3N4复合材料制备及其光催化降解抗生素性能

Cu2O/Ag/g-C3N4复合材料制备及其光催化降解抗生素性能

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采用水热法和原位光还原法制备一系列Cu2O/Ag/g-C3N4复合材料,采用XRD、IR、PL等对复合材料进行表征,并测试其光催化性能.结果表明,Ag和Cu2 O成功负载到g-C3 N4表面,且没有破坏g-C3 N4的结构;当溶液pH=6时,20 mg 15%-Cu2 O/Ag/g-C3 N4对四环素降解率为94.3%.·OH、·O2-、h+对Cu2 O/Ag/g-C3 N4降解四环素起主要作用.光催化性能提升的原因可能是由于Ag和Cu2 O的加入形成异质结,增大g-C3 N4的比表面积,降低其带隙能,使其在可见光区的吸收增强,抑制光生电子-空穴对的复合,提高了g-C3 N4光催化性能.
Synthesis of Cu2 O/Ag/g-C3N4 composites and its photocatalytic degradation of antibiotic
A series of Cu2O/Ag/g-C3N4 complexes were prepared by hydrothermal and in situ photoreduc-tion methods and characterized by XRD,IR,PL.The photocatalysis performance of the complexes was tested.Experimental results show that Ag and Cu2O are loaded onto the surface of g-C3N4 without dama-ging its structure.The degradation conversion of tetracycline was 94.3% when the solution pH=6 and 20 mg 15%-Cu2O/Ag/g-C3N4 was used.The·OH,·O2-,and h+play major role in degradation of tetracycline over Cu2O/Ag/g-C3N4 .The improved photocatalytic performance of catalyst may be due to increasing specific surface area of g-C3N4 after addition of Ag and Cu2O to form heterojunctions,decreasing of band gap energy resulting in increased absorption range in the visible region,and inhibiting in recombina-tion of photogenerated electron-hole pairs.

catalytic chemistryCu2Og-C3N4tetracyclinephoto-Fenton-like catalysis

林诗音、张宇航、谢继苗、毛娜

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渭南师范学院,陕西 渭南714099

催化化学 Cu2O g-C3N4 四环素 光-类Fenton催化

陕西省教育厅重点实验室项目渭南市科技局项目渭南师范学院大学生创新训练计划项目渭南师范学院大学生创新训练计划项目

20JS0462021ZDYF-JCYJ-282202310723020S202310723051

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(7)