工业催化2024,Vol.32Issue(7) :43-48.DOI:10.3969/j.issn.1008-1143.2024.07.008

Cu2O/Ag/g-C3N4复合材料制备及其光催化降解抗生素性能

Synthesis of Cu2 O/Ag/g-C3N4 composites and its photocatalytic degradation of antibiotic

林诗音 张宇航 谢继苗 毛娜
工业催化2024,Vol.32Issue(7) :43-48.DOI:10.3969/j.issn.1008-1143.2024.07.008

Cu2O/Ag/g-C3N4复合材料制备及其光催化降解抗生素性能

Synthesis of Cu2 O/Ag/g-C3N4 composites and its photocatalytic degradation of antibiotic

林诗音 1张宇航 1谢继苗 1毛娜1
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作者信息

  • 1. 渭南师范学院,陕西 渭南714099
  • 折叠

摘要

采用水热法和原位光还原法制备一系列Cu2O/Ag/g-C3N4复合材料,采用XRD、IR、PL等对复合材料进行表征,并测试其光催化性能.结果表明,Ag和Cu2 O成功负载到g-C3 N4表面,且没有破坏g-C3 N4的结构;当溶液pH=6时,20 mg 15%-Cu2 O/Ag/g-C3 N4对四环素降解率为94.3%.·OH、·O2-、h+对Cu2 O/Ag/g-C3 N4降解四环素起主要作用.光催化性能提升的原因可能是由于Ag和Cu2 O的加入形成异质结,增大g-C3 N4的比表面积,降低其带隙能,使其在可见光区的吸收增强,抑制光生电子-空穴对的复合,提高了g-C3 N4光催化性能.

Abstract

A series of Cu2O/Ag/g-C3N4 complexes were prepared by hydrothermal and in situ photoreduc-tion methods and characterized by XRD,IR,PL.The photocatalysis performance of the complexes was tested.Experimental results show that Ag and Cu2O are loaded onto the surface of g-C3N4 without dama-ging its structure.The degradation conversion of tetracycline was 94.3% when the solution pH=6 and 20 mg 15%-Cu2O/Ag/g-C3N4 was used.The·OH,·O2-,and h+play major role in degradation of tetracycline over Cu2O/Ag/g-C3N4 .The improved photocatalytic performance of catalyst may be due to increasing specific surface area of g-C3N4 after addition of Ag and Cu2O to form heterojunctions,decreasing of band gap energy resulting in increased absorption range in the visible region,and inhibiting in recombina-tion of photogenerated electron-hole pairs.

关键词

催化化学/Cu2O/g-C3N4/四环素/光-类Fenton催化

Key words

catalytic chemistry/Cu2O/g-C3N4/tetracycline/photo-Fenton-like catalysis

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基金项目

陕西省教育厅重点实验室项目(20JS046)

渭南市科技局项目(2021ZDYF-JCYJ-282)

渭南师范学院大学生创新训练计划项目(202310723020)

渭南师范学院大学生创新训练计划项目(S202310723051)

出版年

2024
工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
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