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铁钴比例对碳材料形貌及析氧反应活性的影响

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通过电催化分解水反应获得可持续氢能源是替代不可再生化石能源的有效途径.开发高效的析氧催化剂是解决析氧动力学缓慢,提高电解水反应的关键.过渡金属钴、铁是高效的电催化分解水催化剂,同时它们可以催化碳源得到高导电性的碳纳米管材料.通过铁源(乙酰丙酮铁)和钴源(硝酸钴)与石墨相氮化碳(g-C3 N4)的高温固相反应,采用扫描电镜和X射线衍射表征,研究不同铁/钴比例对合成碳材料形貌的影响,并通过电催化析氧反应和双电层电容实验研究材料的电化学性能.结果表明,Co9 Fe1@NCNTs电催化剂的OER活性最高,双电层电容值最大.
Effect of iron-cobalt ratio on the morphology and oxygen evolution reaction activity of carbon materials
To obtain sustainable hydrogen energy through electrocatalytic decomposition of water is an effective way to replace non-renewable fossil energy.The development of efficient oxygen evolution catalyst is the key to solve the problem of slow oxygen evolution kinetics and increase water electrolysis reac-tion.Transition metals cobalt and iron are efficient electrocatalytic catalysts for water decomposition,and they can catalyze carbon source to produce carbon nanotube materials with high conductivity.In this paper,the source of iron (iron acetylacetonate),cobalt (cobalt nitrate) and graphite carbon nitride (g-C3N4) were mixed for high temperature solid phase reaction.Using scanning electron microscopy (SEM) and X-ray diffraction (XRD) characterization were used to study the effect of different Fe/Co ratio on the synthesized carbon materials morphology.Electrochemical performance of the materials were tested by electrocatalytic oxygen evolution reactions and electric double layer capacitance experiment.The results showed that Co9 Fe1@NCNTs had the highest activity for OER and highest value of electric double layer capacitance

catalyst engineeringtransition metalcarbon nitridecarbon materialsmorphologyoxygen evolution reaction

包沙日勒敖都、李鑫

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通辽市市场检验检测中心,内蒙古 通辽028000

通辽市生态环境局经济开发区分局,内蒙古 通辽028000

催化剂工程 过渡金属 氮化碳 碳材料 形貌 析氧反应

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(7)