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橡胶用间苯二酚甲醛树脂的合成

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以间苯二酚、苯乙烯和甲醛为原料合成间苯二酚甲醛树脂,考察不同催化剂和工艺条件对合成树脂性能的影响.结果表明,以对甲苯磺酸为催化剂,调整物质的量等反应条件,可制得软化点109℃的间苯二酚甲醛树脂,以间苯二酚甲醛树脂制备的硫化橡胶硫化性能和物理性能与采用间苯二酚制备的硫化橡胶相当,满足目前子午线轮胎粘合的需要.
Synthesis of resorcinol formaldehyde resin for rubber
Resorcinol formaldehyde resin was synthesized from resorcinol,styrene and formalde-hyde.Effects of catalyst and reaction conditions on properties of resin were investigated.The results showed that resorcinol formaldehyde resin with softening point of 109 ℃ could be prepared by using p-toluenesulfonic acid as catalyst and adjusting the reaction conditions such as the amount of substances.The vulcanized rubber prepared with resorcinol formaldehyde resin has the same vulcanization and physical properties as the vulcanized rubber prepared with resorcinol,which meets the needs of current radial tire adhesion.

oganic chemical engineeringresorcinolp-toluenesulfonic acidresorcinol formaldehyde resinvulcanization

王罡、马少波、张玮

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西安元创化工科技股份有限公司,陕西 西安710061

有机化学工程 间苯二酚 对甲苯磺酸 间苯二酚甲醛树脂 硫化

陕西省重点研发计划项目

2018ZDXM-GY-160

2024

工业催化
西北化工研究院

工业催化

CSTPCD
影响因子:0.504
ISSN:1008-1143
年,卷(期):2024.32(7)