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直流电晕放电协同膜蒸馏处理含盐废水的研究

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膜蒸馏技术因能量需求与盐度无关,尤其适合处理高盐度水体,但低膜通量是限制其广泛应用的技术瓶颈.文中采用电晕放电协同膜蒸馏的手段,在不同电极结构、电压极性和放电强度下,研究了电晕放电对聚偏氟乙烯(polyvinylidene fluoride,PVDF)疏水膜膜蒸馏过程的影响.实验发现:膜通量促进效果与电极结构有关,且存在极性效应.在单针和多针电晕放电下,PVDF膜通量可由0.108 g/(cm2·h)提高到0.146 g/(cm2·h),电晕停止后,膜通量恢复至初始水平.文中研究表明,将电晕放电和膜蒸馏相结合可以提高膜通量,并且电晕放电对PVDF疏水膜无破坏.在电晕辅助膜蒸馏过程中,薄膜上方荷电液滴的定向电泳对膜通量起一定程度的抑制作用,而离子风的形成及发展起促进作用.
Study on Treatment of Saline Wastewater by DC Corona Discharge in Cooperation with Membrane Distillation
Membrane distillation technology is particularly suitable for the treatment of treating high salinity waters due to independent of energy requirement from salinity.However,the low membrane flux is the technical bottleneck that limits its wide application.In this paper,the influence of corona discharge on membrane distillation process of polyvinylidene fluoride(PVDF)hydrophobic membrane is studied by means of corona discharge coupled with mem-brane distillation under different electrode structures,voltage polarity and discharge intensity.It is found by experi-ment that the membrane flux promotion effect is related to the electrode structure and the polarity effect is existed.In case of single and multiple needle corona discharge,the membrane flux can be increased from 0.108 g/(cm2·h)to 0.146 g/(cm2·h).After the stop of the corona discharge the membrane flux is recovered to is initial level.The study in this paper shows that the combination of corona discharge and membrane distillation can improve membrane flux and that the corona discharge does not damage PVDF hydrophobic membranes.During corona-assisted membrane distil-lation,the directional electrophoresis of charged droplets above the film plays a certain degree of inhibition on the membrane flux,while the formation and development of ionic wind play a facilitating role.

corona dischargepolyvinylidene fluoride(PVDF)membrane distillationion wind

杨国清、单繁、王德意、张梦烨、徐佳英

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西安理工大学电气工程学院,西安 710054

西北旱区生态水利国家重点实验室,西安 710054

电晕放电 聚偏氟乙烯 膜蒸馏 离子风

2025

高压电器
西安高压电器研究所

高压电器

北大核心
影响因子:1.354
ISSN:1001-1609
年,卷(期):2025.61(1)