首页|高温高压对三元预混燃料爆炸特性的影响

高温高压对三元预混燃料爆炸特性的影响

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乙醇/甲烷/氢气(C2H5OH/CH4/H2)作为一种新型的替代燃料,研究其爆炸特性对于我国新能源的可持续发展具有重要意义.在不同的当量比(0.8~1.4)、初始压力(0.1、0.2 和0.4 MPa)和初始温度(370、400 和 450 K)下,从实验和化学动力学角度分析了其对关键爆炸特性参数,如峰值爆炸压力、峰值爆炸压力上升速率、爆炸时间以及爆燃指数的影响.结果表明,爆炸特性参数在当量比为 1.2~1.3 之间时出现极值.峰值爆炸压力与初始压力呈线性正相关,而与初始温度呈线性负相关.增大初始压力,火焰锋面裂纹、胞化程度加深,峰值爆炸压力增大.此外,实验工况下评估的最大爆燃指数为 20.83 MPa·m/s,表明预混燃料的燃烧处于相对安全水平.基元反应敏感性分析表明:爆燃反应与H和OH自由基密切相关,而R1、R8、R24、R96 是影响爆炸反应强度最重要的 4 个基元反应.研究成果可为C2H5OH/CH4/H2 三元混合燃料在实际燃烧装置中的应用、燃料安全性评估以及爆炸事故预防提供参考.
Effect of High Temperature and High Pressure on the Explosion Characteristics of Ternary Premixed Fuel
As a new alternative fuel,ethanol/methane/hydrogen(C2H5OH/CH4/H2)is of great significance for the sustainable development of new energy in China.The effects of different equivalence ratios(0.8-1.4),initial pressures(0.1,0.2 and 0.4 MPa)and initial temperatures(370,400 and 450 K)on key explosion characteristics such as peak explosion pressure,peak explosion pressure rise rate,explosion time and deflagration index were analyzed from the experimental and chemical kinetics perspectives.The results show that the explosion characteristic parameters exhibit extreme values when the equivalence ratios between 1.2 and 1.3.The peak explosion pressure is positively correlated with initial pressure and negatively correlated with initial temperature,and this correlation is linear.With the increase in initial pressure,the crack and cytochemical degree of the flame front deepened,and the peak explosion pressure increased.In addition,the maximum deflagration index evaluated under experimental conditions was 20.83 MPa·m/s,indicating that the combustion of premixed fuel/air was at a relatively safe level.The reaction sensitivity analysis of the motives showed that the deflagration reaction was closely related to the H and OH radicals,and R1,R8,R24 and R96 were the top four motif reactions that had the most important impact on the explosion reaction intensity.This work can provide a valuable reference for the application of C2H5OH/CH4/H2 ternary mixed fuel in actual combustion units,the evaluation of fuel safety,and the prevention of explosion accidents.

ethanol/methane/hydrogenexplosive characteristicslinear correlationH and OH free radicals

朱源、姜根柱、王筱蓉、郭宏展、苏傲成

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江苏科技大学机械工程学院,江苏 镇江 212003

乙醇/甲烷/氢气 爆炸特性 线性相关 H和OH自由基

2025

高压物理学报
中国物理学会 高压物理专业委员会 四川省物理学会

高压物理学报

北大核心
影响因子:0.276
ISSN:1000-5773
年,卷(期):2025.39(1)