首页|MnO2促进厌氧氨氧化工艺启动的试验研究

MnO2促进厌氧氨氧化工艺启动的试验研究

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为了考察投加MnO2对ANAMMOX工艺启动效果和脱氮性能的促进作用,通过改变水力负荷以及采用逐级驯化手段,向反应器中投加MnO2(0~50 mg/L),逐步提高厌氧氨氧化污泥对MnO2耐受性,运行90 d成功启动ANAMMOX反应器.反应器对NH4+-N、NO2--N去除率分别稳定在78%、98%,NLR可提升至0.855 kg/(m3·d),NRR稳定在0.718 kg/(m3·d)左右,NO2--N与NH4+-N物质的量比以及NO3--N与NH4+-N物质的量比分别稳定在1.32和0.20,SAA数值最大为269.86 mg[N]/(g[VSS]·d),利用高通量测序技术进行微生物群落结构分析,AnAOB属占比8.92%,成为优势菌属.相较于传统ANAMMOX工艺,投加MnO2可促进AnAOB的富集、强化AnAOB的活性,为ANAMMOX工艺广泛应用于实际工程提供参考.
Experimental study on MnO2 promoting start-up of ANAMMOX process
In order to investigate the promotional effect of MnO2 addition on start-up effect and denitrification performance of ANAMMOX process,by changing hydraulic load and adopting step-by-step domestication means to add MnO2(0-50 mg/L)to the reactor,the tolerance of anaerobic ammonia oxidation sludge to MnO2 was gradually improved and the ANAMMOX reactor was successfully started-up for 90 d of operation.The removal rates of NH4+-N and NO2-N were stabilized at 78%and 98%respectively,the NLR was enhanced to 0.855 kg/(m3·d),the NRR was stabilized at about 0.718 kg/(m3·d),and the mass ratios of NO2--N to NH4+-N and NO3--N to NH4+-N were stabilized at 1.32 and 0.20 respectively,and the maximum value of SAA was 269.86 mg[N]/(g[VSS]·d),and the microbial community structure analysis using high-throughput sequencing technology showed that the genus AnAOB accounted for 8.92%,and became the dominant genus.Compared to the traditional ANAMMOX process,the addition of MnO2 can promote the enrichment of AnAOB and strengthen the activity of AnAOB,which can provide a reference for the wide application of ANAMMOX process in practice.

MnO2ANAMMOXbiological nitrogen removalUASB reactormicrobial community structureAnAOB activity

耿诗雯、李军、李光蕾、李俊鹏

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沈阳建筑大学市政与环境工程学院,沈阳 110168

MnO2 厌氧氨氧化 生物脱氮 UASB反应器 微生物群落结构 AnAOB活性

国家自然科学基金项目

51108277

2024

工业用水与废水
东化工程科技股份有限公司

工业用水与废水

CSTPCD
影响因子:0.649
ISSN:1009-2455
年,卷(期):2024.55(2)
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