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短程硝化-厌氧氨氧化工艺的快速启动策略研究

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针对短程硝化-厌氧氨氧化(PN-Anammox)耦合工艺在实际应用中存在的启动困难及运行不稳定等问题,提出了一种基于曝气量与溶解氧(DO)联合控制的快速启动策略.在维持低DO环境(<0.2 mg/L)的条件下,通过逐步调节曝气量(100~175 L/h),精确控制反应体系的供氧量,以确保为厌氧氨氧化(Anammox)过程提供所需的亚硝态氮,从而实现PN与Anammox的高效耦合.研究结果显示,当进水总氮负荷为533.3 mg/(L·d),DO的质量浓度为0.04~0.15 mg/L,曝气量为175 L/h时,PN-Anammox耦合工艺表现出最佳的脱氮性能,总氮去除率达到77.6%,总氮去除速率为423.5 mg/(L·d).在低DO环境下,氨氧化菌(AOB)与厌氧氨氧化菌(AnAOB)的原位活性随着曝气量的增加而显著增强.工艺成功启动后,AnAOB活性仅发挥出最大潜力的51.3%(929.3 mg/(L·d)),显示出系统较强的脱氮潜力及抗负荷冲击能力.此外,载体生物膜中亚铁血红素C(HemeC)含量和联氨脱氢酶(HDH)活性分别为絮体污泥的1.3倍和4.6倍,分别为1.21 mmol/g和0.09 μmol/(g·min),这说明投加载体有助于AnAOB的生长富集,从而有利于反应器的稳定运行.通过该联合控制策略,仅用39d便在序批式反应器(SBR)中成功启动了 PN-Anammox耦合工艺,并在高氨氮废水处理中表现出优异的脱氮效果.
Study on strategies of rapid start-up of partial nitrification-anammox process
A rapid start-up strategy based on aeration and dissolved oxygen(DO)combined control was proposed to solve the start-up difficulties and instability of partial nitrification-anammox(PN-Anammox)cou-pling process in practical application.Under the condition of maintaining a low DO environment(<0.2 mg/L),the oxygen supply of the reaction system was precisely controlled by gradually adjusting the aeration rate(100~175 L/h)to ensure that nitrite nitrogen is provided for the anaerobic ammonia oxidation(Anammox)process,so as to achieve efficient coupling of PN and Anammox.The results showed that when the total nitrogen load of in-fluent water was 533.3 mg/(L·d),the mass concentration of DO was 0.04-0.15 mg/L,and the aeration rate was 175 L/h,the PN-Anammox coupling process showed the best nitrogen removal performance,and the total nitro-gen removal rate reached 77.6%,the removal speed was 423.5 mg/(L·d).In low DO environment,the in situ activities of AOB and AnAOB were significantly enhanced with the increase of aeration rate.After the process was successfully started,the AnAOB activity only reached 51.3%(929.3 mg/(L·d))of the maximum potential,which showed that the system had strong nitrogen removal potential and load shock resistance.In addition,the content of Heme C and the activity of hydrazine dehydrogenase(HDH)were 1.3 and 4.6 times of that of floc sludge,which were 1.21 mmol/g and 0.09 pmol/(g·min)respectively.The addition of carrier is conducive to the growth and enrichment of AnAOB,thereby was beneficial to the stable operation of the reactor.Through the joint control strategy,the PN-anammox coupling process was successfully started in sequence batch reactor(SBR)in only 39 days,and showed excellent nitrogen removal effect in the treatment of high ammonia nitrogen wastewater.

partial nitrificationanaerobic ammonia oxidationaeration ratedissolved oxygencarrier

李林曦、张子锟、李晓、吴伟鹏、林钰婷、念克阳

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厦门峻鸿环境固废处置有限公司,福建 厦门 361101

厦门大学环境与生态学院,福建 厦门 361102

短程硝化 厌氧氨氧化 曝气量 溶解氧 载体

2024

工业用水与废水
东化工程科技股份有限公司

工业用水与废水

CSTPCD
影响因子:0.649
ISSN:1009-2455
年,卷(期):2024.55(6)