环三藜芦烃金属配合物的合成、表征及荧光性能研究

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中文摘要：利用配体前体HECTV(5,6,12,13,19,20-六咪唑-乙氧基环三藜芦烃)与Zn(CH3COO)2·4H2O、Cd(CH3COO)2·4H2O、H2bdc(间苯二甲酸)和OH-H2bdc(5-羟基间苯二甲酸),通过优化反应温度、溶剂等因素,自组装合成了三个结构新颖的化合物.[Zn6(HECTV)(bdc)5(HCOO)2]·4DMF·2H2O(1),[Cd3(HECTV)(bdc)3]·6.5H2O(2),[Cd3(HECTV)(OH-bdc)2(H2O)2]·DMF·2H2O(3).化合物1～3展示了不同的二维或者三维的结构.有机羧酸配体的差异导致合成的配合物结构变化很大.此外,我们研究了化合物1～3的发光性质.

外文标题：Synthesis,Characterization and Fluorescence Properties of Metal Complexes of Cyclododecane

外文摘要：Three structurally novel compounds were synthesized by self-assembly using the ligand precursor HECTV(5,6,12,13,19,20-hexaimidazol-ethoxycyclohexene)with Zn(CH3COO)2·4H2O,Cd(CH3COO)2·4H2O,H2bdc(isophthalic acid),and OH-H2bdc(5-hydroxyisophthalic acid)by optimizing reaction temperature,solvent,and other factors.[Zn6(HECTV)(bdc)5(HCOO)2]·4DMF·2H2O(1),[Cd3(HECTV)(bdc)3]·6.5H2O(2),[Cd3(HECTV)(OH bdc)2(H2O)2]·DMF·2H2O(3).Compounds 1 to 3 exhibited different two-dimensional or three-dimensional structures.The differences in organic carboxylic acid ligands led to significant structural changes in the synthesized complexes.In addition,the luminescent properties of compounds 1 to 3 were investigated.

外文关键词：

cyclotriaromatic hydrocarbonscomplexsynthesisfluorescence

作者：

康大伟、高红梅、赵新宇、徐宁

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作者单位：

内蒙古民族大学化学与材料学院,内蒙古自治区天然产物化学与功能分子合成重点实验室,内蒙古通辽 028000

关键词：

环三藜芦烃配合物合成荧光

出版年：

2025

DOI：