广州化工2025,Vol.53Issue(1) :42-46.DOI:10.20220/j.cnki.1001-9677.2025.01.012

荧光铜纳米粒的合成及其温度传感性能

Synthesis and Temperature Sensing Properties of Fluorescent Copper Nanoparticles

高舞阳 石琳 马天锋 徐小花 芦永昌 林鹏程 王欢 李容榕
广州化工2025,Vol.53Issue(1) :42-46.DOI:10.20220/j.cnki.1001-9677.2025.01.012

荧光铜纳米粒的合成及其温度传感性能

Synthesis and Temperature Sensing Properties of Fluorescent Copper Nanoparticles

高舞阳 1石琳 1马天锋 1徐小花 1芦永昌 1林鹏程 1王欢 1李容榕1
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作者信息

  • 1. 青海民族大学药学院,青海 西宁 810007
  • 折叠

摘要

以五水硫酸铜(CuSO4·5H2O)为铜源,抗坏血酸(AA)作为还原剂和保护剂,通过液相化学还原法成功合成了荧光铜纳米粒(CuNPs).该CuNPs具有激发波长依赖性,最大发射波长为440 nm,呈现蓝色荧光.分别用透射电子显微镜(TEM)、紫外-可见吸收光谱(UV-Vis)、荧光光谱(FL)、傅里叶变换红外光谱(FT-IR)、能量色散谱(EDS)、X射线衍射谱(XRD)、动态光散射谱(DLS)和ZETA电位谱对CuNPs结构及其光学特性进行了表征.研究发现,所合成的CuNPs在25~85 ℃温度范围内具有温度传感特性,计算出最大相对测温灵敏度为1.95%·℃-1.研究结果表明所合成的CuNPs在温度传感方面显示出潜在的应用价值.

Abstract

Fluorescent copper nanoparticles(CuNPs)were successfully synthesized by a liquid-phase chemical reduction method using copper sulfate pentahydrate(CuSO4·5H2O)as the copper source and anti-cyclic hematoxylin acid(AA)as the reducing and protective agent.CuNPs had an excitation wavelength dependence with a maximum emission wavelength of 440 nm and showed blue fluorescence.CuNPs structures and their optical properties were characterized by transmission electron microscope(TEM),ultraviolet and visible spectrophotometry(UV-Vis),fluorescence spectroscopy(FL),fourier transform infrared spectroscopy(FT-IR),energy dispersive spectroscopy(EDS),diffraction of X-rays(XRD),dynamic light scattering(DLS)and ZETA potential spectroscopy,respectively.The synthesized CuNPs were found to have temperature sensing properties in the temperature range of 25 to 85 ℃,with a calculated maximum relative temperature sensitivity of 1.95%·℃-1.The results indicated that the synthesized CuNPs showed potential applications in temperature sensing.

关键词

液相化学还原法/荧光铜纳米粒/温度传感

Key words

liquid-phase chemical reduction/fluorescent copper nanoparticles/temperature sensing

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出版年

2025
广州化工
广州市化工行业协会 广州市化学化工学会 广州市化学工业研究所

广州化工

影响因子:0.358
ISSN:1001-9677
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