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基于溶解度参数的废润滑油精制溶剂选择

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废润滑油兼具显著的污染性和潜在的资源价值,其中90%左右的未变质基础油仍然可以重新利用,借助溶剂再生技术实现废油的无害化处理可以避免对环境的污染,提高资源利用效率。本文以溶解度参数理论为依据,根据润滑油的使用性能对润滑油理想组分结构进行分析,通过润滑油的使用条件推算变质组分的结构,利用Fedors基团贡献法对理想组分与变质组分的溶解度参数进行估算,为废润滑油精制溶剂选择提供帮助。通过计算可得润滑油理想组分的溶解度参数在16。45~18。89 J-1/2·3 cm3/2之间,润滑油变质组分的溶解度参数在17。56~24。61 J-1/2·cm3/2之间。为了让变质组分与溶剂有良好的相容性并降低理想组分在溶剂中的溶解性,应优先选取溶解度参数在20~23 J-1/2·cm3/2之间的溶剂。
Solvent Selection for Waste Lubricating Oil Refining Based on Solubility Parameters
Waste lubricating oil has both significant pollution and potential resource value,about 90%of the undeteriorated base oil can still be reused,and the harmless treatment of waste oil with solvent recycling technology can avoid environmental pollution and improve resource utilization efficiency.Based on the solubility parameter theory,this the structure of ideal components of lubricating oil according to the performance of lubricating oil was analyzed,the structure of deteriorated components was calculated according to the use conditions of lubricating oil,and Fedors group contribution method was used to estimate the solubility parameters of ideal components and deteriorated components,providing help for the selection of waste lubricating oil refining solvent.The solubility parameters of ideal components of l ubricating oil ranged from 16.45 to 18.89 J-1/2·cm3/2,and that of deteriorated components ranged from 17.56 to 24.61 J-1/2·cm3/2.In order to make the metamorphic component have good compatibility with the solvent and reduce the solubility of the ideal component in the solvent,the solvent with the solubility parameter between 20 and 23 J-1/2·cm3/2 should be selected preferentially.

spent lubricating oilsolventsolubility parameterideal componentmetamorphic component

班秀涛、屈思旭、王九州

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西安石油大学化学化工学院,陕西 西安 710065

废润滑油 溶剂 溶解度参数 理想组分 变质组分

2025

广州化工
广州市化工行业协会 广州市化学化工学会 广州市化学工业研究所

广州化工

影响因子:0.358
ISSN:1001-9677
年,卷(期):2025.53(1)