首页|黄皮多糖/壳聚糖复合可食膜的制备、结构表征及理化性质

黄皮多糖/壳聚糖复合可食膜的制备、结构表征及理化性质

Preparation,Structural Characterization and Physicochemical Properties of Wampee Polysaccharide/Chitosan Composite Edible Film

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采用水提醇沉法提取黄皮多糖(WSP-W)并将其同壳聚糖复合,制备成WSP-W/壳聚糖复合可食膜,初步测定WSP-W分子量、化学组成、红外光谱,并且考察WSP-W对壳聚糖复合可食膜的影响.结果表明,WSP-W是一种典型的均一多糖,分子量为1.6×103 ku.复合膜的FT-IR中壳聚糖分子的氨基带从1 560.1 cm-1移动到了1 571.7 cm-1,表明WSP-W和壳聚糖之间存在相互作用力.与单一壳聚糖膜相比,复合膜的厚度、水溶解性、溶胀率增加,水分含量降低.在光学透过率方面,波长小于500 nm时,复合膜的紫外阻隔能力较强.机械性能的研究结果显示,在WSP-W添加量为12%时,拉伸强度和断裂伸长率均达到最大值,分别为30.13 MPa和29.93%.水蒸气透过率在 WSP-W 12%时达 24.54g mm/(m2·d·kPa),在 WSP-W 6%时,阻油性能达 96.24 g·mm/(m2·d).DSC 结果表明,复合膜的热稳定性更佳.DPPH自由基清除率和羟基自由基清除率(最大达99.85%)结果表明WSP-W可以提高复合膜的抗氧化活性.综上所述,WSP-W的加入能够改善单一壳聚糖膜的光学性能、力学性能、阻隔性能、抗氧化性,可为黄皮多糖的开发利用提供一定的参考.
Water-soluble polysaccharide from wampee(WSP-W)was prepared through water extraction then precipitation by ethanol,and compounded with chitosan to make WSP-W/chitosan composite edible films.The molecular weight,chemical composition and infrared spectrum of WSP-W were preliminarily examined,and the effect of WSP-W on the WSP-W/chitosan composite edible film was investigated.The results showed that WSP-W was a typical homogeneous polysaccharide,with a molecular weight of 1.6x103 ku.When different concentrations of WSP-W were added,fourier transform infrared spectroscopy demonstrated that The amino band of chitosan molecule in FT-IR spectra shifted from 1 560.1 cm-1 to 1 571.7 cm-1 for the composite film,indicating that there was an interaction between WSP-W and chitosan.Compared with the film made with chitosan singly,the composite films exhibited increased thickness,water solubility and swelling rate but a decreased moisture content.In terms of optical transmittance,the composite films showed strong UV barrier capability at a wavelength below 500 nm.The results of the mechanical property tests showed that when the WSP-W content was 12%,the tensile strength and elongation at break reached the maximum(30.13 MPa and 29.93%,respectively).The water vapor permeability reached 24.54 g·mm/(m2·d·kPa)when WSP-W was 12%,and the oil resistance capacity reached 96.24 g·mm/(m2·d)when WSP-W was 6%.DSC results revealed that the thermal stability of the composite films was better.The results of the DPPH and hydroxyl radical scavenging rates showed that WSP-W could improve the film's antioxidant activity.In summary,the addition of WSP-W can improve the optical,mechanical,barrie and antioxidant properties of chitosan film,which can provide a certain reference for the development and utilization of WSP.

edible filmchitosanwampeestructural characterisationantioxidant activity

方娟丽、熊群燕、龚锐枝、刘冰茹、孙朋朋、任圆圆

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长江大学生命科学学院,湖北荆州 434025

可食性膜 壳聚糖 黄皮 结构特征 抗氧化性

食品营养与安全国家重点实验室开放课题长江大学大学生创新创业训练计划项目

SKLFNS-KF-202108Yz2022233

2024

现代食品科技
华南理工大学

现代食品科技

CSTPCD北大核心
影响因子:1.07
ISSN:1673-9078
年,卷(期):2024.40(8)