首页|氧化石墨烯表面接枝抗菌聚合物的研究

氧化石墨烯表面接枝抗菌聚合物的研究

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研究了一种制备两性离子聚合物修饰的抗菌氧化石墨烯(GO-PSBMA)的方法.基于氧化石墨烯(GO)表面含有大量的-OH,采用酯化反应制备了具有大量溴引发位点的GO(GO-Br).使用甲基丙烯酸磺基甜菜碱(SBMA)作为聚合单体,通过表面引发的原子转移自由基聚合(SI-ATRP)在GO-Br表面进行聚合.用聚合物改性的GO对大肠杆菌表现出99.99%的抗菌活性.本研究有效地建立了对氧化石墨烯的新型聚合物改性方法,赋予其优异的抗菌性能.
Study on Grafting the Antibacterial Polymer on the Surface of Graphene Oxide
A method for preparing antibacterial graphite oxide(GO-PSBMA)modified by zwitter-ionic polymer brush was studied.GO(GO-Br)with a large number of bromine initiation sites was prepared by esterification based on the large amount of-OH on the surface of graphene oxide(GO).Methacrylate sulfobetaine(SBMA)was used as the polymerization monomer and polymerized on the surface of GO-Br by surface-initiated atomic transfer radical polymerization(SI-ATRP).GO modified with polymer brush showed 99.99%antibacterial activity against E.coli.A novel polymer modification method for graphene oxide was effectively established,which endows it with excellent antibacterial properties.

graphene oxidesurface graftingantibacterial polymer

李邦森、朱文雅、尹非凡、石建军、覃怀德、史载锋

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海南师范大学 化学与化工学院,海南省水污染治理与资源化重点实验室,海南 海口 571158

中国热带农业科学院 橡胶研究所,海南 海口 571101

氧化石墨烯 表面接枝 抗菌聚合物

2024

海南师范大学学报(自然科学版)
海南师范大学

海南师范大学学报(自然科学版)

影响因子:0.271
ISSN:1674-4942
年,卷(期):2024.37(3)